Functionalization of carbon nanotubes with biodegradable supramolecular polypseudorotaxanes from grafted-poly(ε-caprolactone) and α-cyclodextrins
作者： Yingkui Yang , Chi Pong Tsui , Chak Yin Tang , Shengqiang Qiu , Qiang Zhao
DOI: 10.1016/J.EURPOLYMJ.2009.10.020
关键词:
摘要: Abstract Functionalization of multiwalled carbon nanotubes (MWNTs) with biodegradable supramolecular polypseudorotaxanes has been successfully performed by utilizing surface-initiated ring-opening polymerization e-caprolactone (CL) to yield poly(e-caprolactone)-grafted MWNTs (MWNT-g-PCL), followed forming inclusion complexes between grafted-PCL chains and α-cyclodextrins (α-CDs) give α-CD-NTPCL hybrids. There are significant differences in the morphology solubility before after introduction α-CD. Some protuberances clearly observed for as compared MWNT-g-PCL. Furthermore, host–guest stoichiometry (monomeric unit CL/α-CD molar ratio) is much higher than that consisted linear PCL α-CDs. This observation can be explained a combination several reasons including steric hindrance grafted-PCL, competitive exclusion adjacent toward α-CD, addition order α-CD well feed ratio. The present methodology may open up new opportunity application chemistry chemical manipulation processing CNTs. Moreover, such novel hybrids provide an entry extend applications CNTs medicine biology fields through embedding functional polymers heterogeneous components.
core.ac.uk
elsevier.com
sci-hub.se 参考文章(86)
Brent S. Sumerlin, Nicolay V. Tsarevsky, Guillaume Louche, Robert Y. Lee, Krzysztof Matyjaszewski, Highly Efficient “Click” Functionalization of Poly(3-azidopropyl methacrylate) Prepared by ATRP Macromolecules. ,vol. 38, pp. 7540- 7545 ,(2005) , 10.1021/MA0511245
Volodymyr Senkovskyy, Natalya Khanduyeva, Hartmut Komber, Ulrich Oertel, Manfred Stamm, Dirk Kuckling, Anton Kiriy, Conductive Polymer Brushes of Regioregular Head-to-Tail Poly(3-alkylthiophenes) via Catalyst-Transfer Surface-Initiated Polycondensation Journal of the American Chemical Society. ,vol. 129, pp. 6626- 6632 ,(2007) , 10.1021/JA0710306
Cristian C. Rusa, Alan E. Tonelli, Polymer/Polymer Inclusion Compounds as a Novel Approach To Obtaining a PLLA/PCL Intimately Compatible Blend Macromolecules. ,vol. 33, pp. 5321- 5324 ,(2000) , 10.1021/MA000746H
J. N. Coleman, U. Khan, Y. K. Gun'ko, Mechanical Reinforcement of Polymers Using Carbon Nanotubes Advanced Materials. ,vol. 18, pp. 689- 706 ,(2006) , 10.1002/ADMA.200501851
Xintao Shuai, Min Wei, Francis E. Porbeni, Todd A. Bullions, Alan E. Tonelli, Formation of and coalescence from the inclusion complex of a biodegradable block copolymer and alpha-cyclodextrin. 2: A novel way to regulate the biodegradation behavior of biodegradable block copolymers. Biomacromolecules. ,vol. 3, pp. 201- 207 ,(2002) , 10.1021/BM015609M
Erol A. Hasan, Terence Cosgrove, Andrew N. Round, Nanoscale Thin Film Ordering Produced by Channel Formation in the Inclusion Complex of α-Cyclodextrin with a Polyurethane Composed of Polyethylene Oxide and Hexamethylene Macromolecules. ,vol. 41, pp. 1393- 1400 ,(2008) , 10.1021/MA071484N
Kyung-moo Shin, Tungalag Dong, Yong He, Yoichi Taguchi, Akihiro Oishi, Haruo Nishida, Yoshio Inoue, Inclusion Complex Formation between?-Cyclodextrin and Biodegradable Aliphatic Polyesters Macromolecular Bioscience. ,vol. 4, pp. 1075- 1083 ,(2004) , 10.1002/MABI.200400118
Craig J. Hawker, A Simple and Versatile Method for the Synthesis of C60 Copolymers Macromolecules. ,vol. 27, pp. 4836- 4837 ,(1994) , 10.1021/MA00095A027
Fabian Buffa, Hui Hu, Daniel E. Resasco, Side-Wall Functionalization of Single-Walled Carbon Nanotubes with 4-Hydroxymethylaniline Followed by Polymerization of -Caprolactone Macromolecules. ,vol. 38, pp. 8258- 8263 ,(2005) , 10.1021/MA050876W
Neil Ayres, Stephen G. Boyes, William J. Brittain, Stimuli-Responsive Polyelectrolyte Polymer Brushes Prepared via Atom-Transfer Radical Polymerization† Langmuir. ,vol. 23, pp. 182- 189 ,(2007) , 10.1021/LA061526L