Bimetallic heterogeneous catalysts for hydrogen production
作者： Vladimiro Dal Santo , Alessandro Gallo , Alberto Naldoni , Matteo Guidotti , Rinaldo Psaro
DOI: 10.1016/J.CATTOD.2012.07.037
关键词:
摘要: Abstract Polymetallic heterogeneous catalysts, mainly consisting in bimetallic metal nanoparticles supported on inorganic oxides, allow, principle, to obtain high performances (increased activity, and selectivity desired products, extended lifetime, resistance poisoning/coke deposition/sintering/etc.) thanks the positive effects arising from interactions between (two) metals. Due these reasons they are widely used promote a large number of reactions, among them also those aimed hydrogen production. This review examines specific applications reforming (including steam, autothermal/oxidative aqueous phase, dry reforming); catalytic partial oxidations, decomposition, finally water photo-splitting photo-reforming reactions. Applications reviewed with aim highlight both relationships metallic structures properties catalysts identify potential research directions.
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