A novel technique for ready determination of cathodic activity of intermetallic compounds during corrosion of aluminium

作者: K. Shimizu , K. Kobayashi , G.E. Thompson , G.C. Wood

DOI: 10.1016/0010-938X(93)90242-9

关键词:

摘要: Abstract Electron transparent sections of aluminium and its alloys can be generated readily by ultramicrotomy, revealing matrix second phase material upon direct observation in the transmission electron microscope. Detailed examination sections, after retrieval from a water bath located at rear diamond knife used for sectioning, reveals various textures closely adjacent to different compositions. Such texture, associated with extents Al(OH) 3 development, result local alkalinity cathodically active consequent effects on adjacent, filming matrix. This approach thus enables rapid assessment cathodic activity alloys.

参考文章(9)
Norio Sato, Morris Cohen, The Kinetics of Anodic Oxidation of Iron in Neutral Solution Journal of The Electrochemical Society. ,vol. 111, pp. 512- 519 ,(1964) , 10.1149/1.2426170
G.T Burstein, R.J Cinderey, Evolution of the corrosion potential of repassivating aluminium surfaces Corrosion Science. ,vol. 33, pp. 475- 492 ,(1992) , 10.1016/0010-938X(92)90075-E
G.M. Brown, K. Shimizu, K. Kobayashi, G.E. Thompson, G.C. Wood, The growth of chromate conversion coatings on high purity aluminium Corrosion Science. ,vol. 34, pp. 1045- 1054 ,(1993) , 10.1016/0010-938X(93)90288-R
N Cabrera, N F Mott, Theory of the oxidation of metals Reports on Progress in Physics. ,vol. 12, pp. 163- 184 ,(1949) , 10.1088/0034-4885/12/1/308
R.J. Cinderey, G.T. Burstein, The repassivation potential of aluminium in water Corrosion Science. ,vol. 33, pp. 499- 502 ,(1992) , 10.1016/0010-938X(92)90077-G
R.C. Furneaux, G.E. Thompson, G.C. Wood, The application of ultramicrotomy to the electronoptical examination of surface films on aluminium Corrosion Science. ,vol. 18, pp. 853- 881 ,(1978) , 10.1016/0010-938X(78)90009-4
Kenzo KOBAYASHI, Ken-ichi SHIMIZU, Yoshihiro TSUDA, Structure of porous anodic films formed on Al-Si alloys. Journal of Japan Institute of Light Metals. ,vol. 37, pp. 807- 810 ,(1987) , 10.2464/JILM.37.807