A nitro-hunsdiecker reaction: from unsaturated carboxylic acids to nitrostyrenes and nitroarenes.
作者： Jaya Prakash Das , Pradipta Sinha , Sujit Roy
DOI: 10.1021/OL0262901
关键词:
摘要: The nitrodecarboxylation of aromatic α,β-unsaturated carboxylic acids and ring-activated benzoic can be achieved using nitric acid (3 equiv) catalytic AIBN (2 mol %) in MeCN. From the effect various additives, is postulated to involve generation an acyloxy radical RCO2• by a NO3• followed attack NO2• radical.
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