Morphology of polypyrrole films grown in thin-layer cells and on indium-tin oxide conductive glass

作者: J.S. Shapiro , W.T. Smith , C. MacRae

DOI: 10.1016/0032-3861(95)93914-8

关键词:

摘要: Abstract Examination by atomic force microscopy and scanning electron of the non-conducting substrate poly(methyl methacrylate) polypyrrole free-standing film formed at its surface in a thin-layer cell has led to an understanding how such films may be formed. A mechanism is proposed for origin wrinkle morphology observed cells under certain conditions, attention drawn similarity on indium—tin oxide glass electrodes. In both cases it that porous which grows acts as template nucleation sites.

参考文章(15)
Jukka Lukkari, Mika Alanko, Lauri Heikkila, Reino Laiho, Jouko Kankare, Nucleation and growth of poly(3-methylthiophene) on indium-tin oxide glass by scanning tunneling microscopy Chemistry of Materials. ,vol. 5, pp. 289- 296 ,(1993) , 10.1021/CM00027A010
S. J. Sutton, A. S. Vaughan, A novel technique for the examination of internal morphologies in thin film specimens: embedding and etching of polypyrrole Journal of Materials Science. ,vol. 28, pp. 4962- 4969 ,(1993) , 10.1007/BF00361162
H. T. Chiu, J. S. Lin, C. M. Huang, The morphology and conductivity of polypyrrole/polyurethane alloy films Journal of Applied Electrochemistry. ,vol. 22, pp. 358- 363 ,(1992) , 10.1007/BF01092689
Brian R. Saunders, Keith S. Murray, Robert J. Fleming, Yasser Korbatieh, Physical and spectroscopic studies of polypyrrole films containing tetrasulfonated metallophthalocyanine counterions prepared from nonaqueous solution Chemistry of Materials. ,vol. 5, pp. 809- 819 ,(1993) , 10.1021/CM00030A016
Reginald M. Penner, Charles R. Martin, Controlling the Morphology of Electronically Conductive Polymers Journal of The Electrochemical Society. ,vol. 133, pp. 2206- 2207 ,(1986) , 10.1149/1.2108371
Katsuhiko Naoi, Mary Lien, William H. Smyrl, Quartz Crystal Microbalance Study: Ionic Motion Across Conducting Polymers Journal of The Electrochemical Society. ,vol. 138, pp. 440- 445 ,(1991) , 10.1149/1.2085606
G R Mitchell, A Geri, Molecular organisation of electrochemically prepared conducting polypyrrole films Journal of Physics D. ,vol. 20, pp. 1346- 1353 ,(1987) , 10.1088/0022-3727/20/11/002