Imaging NO elimination in the infrared multiphoton dissociation of nitroalkanes and alkyl nitrites
作者： Ravin Fernando , Nuwandi M. Ariyasingha , Arthur G. Suits
DOI: 10.1016/J.CPLETT.2015.12.001
关键词:
摘要: Abstract We present a DC slice imaging study of the decomposition C2, C3 and C4 nitroalkanes alkyl nitrites, focusing on NO elimination channel, possibly minor pathway. Infrared multiphoton dissociation (IRMPD) is used to induce ground electronic state under collisionless conditions. The channels that produced as product were studied compared among target molecules gain better understanding isomerization prior dissociation. Trends in total translational energy rotational temperatures obtained from images are discussed.
harvard.edu
sci-hub.se 参考文章(30)
Ravin Fernando, Chen Qu, Joel M. Bowman, Robert W. Field, Arthur G. Suits, Does Infrared Multiphoton Dissociation of Vinyl Chloride Yield Cold Vinylidene Journal of Physical Chemistry Letters. ,vol. 6, pp. 2457- 2462 ,(2015) , 10.1021/ACS.JPCLETT.5B01031
Qingsheng Wang, Dedy Ng, M. Sam Mannan, Study on the Reaction Mechanism and Kinetics of the Thermal Decomposition of Nitroethane Industrial & Engineering Chemistry Research. ,vol. 48, pp. 8745- 8751 ,(2009) , 10.1021/IE900849N
E.R. Grant, M.J. Coggiola, Y.T. Lee, P.A. Schulz, Aa.S. Sudbo, Y.R. Shen, THE EXTENT OF ENERGY RANDOMIZATION IN THE INFRARED MULTIPHOTON DISSOCIATION OF SF6 Chemical Physics Letters. ,vol. 52, pp. 595- 599 ,(1977) , 10.1016/0009-2614(77)80517-4
A. M. Wodtke, E. J. Hintsa, Yuan T. Lee, Infrared multiphoton dissociation of three nitroalkanes The Journal of Physical Chemistry. ,vol. 90, pp. 3549- 3558 ,(1986) , 10.1021/J100407A019
Xinsheng Zhao, Eric J. Hintsa, Yuan T. Lee, Infrared multiphoton dissociation of RDX in a molecular beam Journal of Chemical Physics. ,vol. 88, pp. 801- 810 ,(1988) , 10.1063/1.454158
Sridhar A. Lahankar, Steven D. Chambreau, Dave Townsend, Frank Suits, John Farnum, Xiubin Zhang, Joel M. Bowman, Arthur G. Suits, The roaming atom pathway in formaldehyde decomposition. Journal of Chemical Physics. ,vol. 125, pp. 044303- 044303 ,(2006) , 10.1063/1.2202241
David W. Chandler, Paul L. Houston, Two‐dimensional imaging of state‐selected photodissociation products detected by multiphoton ionization The Journal of Chemical Physics. ,vol. 87, pp. 1445- 1447 ,(1987) , 10.1063/1.453276
Miho Isegawa, Fengyi Liu, Satoshi Maeda, Keiji Morokuma, Ab initio reaction pathways for photodissociation and isomerization of nitromethane on four singlet potential energy surfaces with three roaming paths Journal of Chemical Physics. ,vol. 140, pp. 244310- 244310 ,(2014) , 10.1063/1.4883916
Aa. S. Sudbo̸, P. A. Schulz, E. R. Grant, Y. R. Shen, Y. T. Lee, Simple bond rupture reactions in multiphoton dissociation of molecules Journal of Chemical Physics. ,vol. 70, pp. 912- 929 ,(1979) , 10.1063/1.437482
Roberta P. Saxon, Megumu Yoshimine, Theoretical study of nitro–nitrite rearrangement of CH3NO2 Canadian Journal of Chemistry. ,vol. 70, pp. 572- 579 ,(1992) , 10.1139/V92-080