On the characteristics of the signal curves of heat flux calorimeters in studies of reaction kinetics: Part 1. A contribution to the desmearing technique

摘要: Abstract In a chemical reaction or in phase transition, the heat production consumption rate is proportional to of conversion. It well known that signal curve flux calorimeter delayed and deformed. order obtain true flow generated by reacting sample, transformation method needed. This often called “desmearing”. There are two techniques for performing transformation. Owing its simplicity based on linear second-order differential equation preferred this paper as desmearing tool, rather than convolution theory. time constants formula. The determination these under real conditions main subject paper. For this, comprehensive mathematical treatment problem necessary.