A Study of the Preparation Procedures of Sulfated Zirconia Prepared from Zirconia Gel. The Effect of the pH of the Mother Solution on the Isomerization Activity ofn-Pentane

作者: Tetsuji Tatsumi , Hiromi Matsuhashi , Kazushi Arata

DOI: 10.1246/BCSJ.69.1191

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摘要: Solid superacids of sulfated zirconia were prepared by the sulfation gels, which obtained from mother solutions with different pH values. The gel precipitated at = 8 gave zirconia, showed highest catalytic activity and selectivity for skeletal isomerization n-pentane. active superacid was high reproducibility upon heating solution, followed washing precipitate hot water; this preparation procedure provided oxide small particle size. could be estimated exothermal peak caused crystallization in DTA.

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