Microphase structure and calculations of the interphase in poly (styrene-b-methylphenylsiloxane) diblock copolymers: a comparative study from small-angle X-ray scattering, electron spectroscopic imaging and solid-state nuclear magnetic resonance

作者: B. Gerharz , A. Du Chesne , G. Lieser , E. W. Fischer , W. Z. Cai

DOI: 10.1007/BF00352907

关键词:

摘要: The microphase structure of a series poly (styrene-b-methylphenylsiloxane) (PS-b-PMPS)-diblock copolymers with various compositions and molecular weights has been studied by small-angle X-ray scattering, electron spectroscopic imaging solid-state nuclear magnetic resonance spectroscopy. This diblock copolymer system is miscible within distinct range temperature weight exhibiting an upper critical solution temperature. three chosen methods which complement each other can be applied to the chemically unmodified model system. results measurements correlate describe structure, domain size interphase.

参考文章(37)
İskender Yilgör, James E. McGrath, Polysiloxane containing copolymers: A survey of recent developments Springer, Berlin, Heidelberg. pp. 1- 86 ,(1988) , 10.1007/BFB0025274
Thomas C. Kendrick, Bhukan M. Parbhoo, James W. White, Polymerization of Cyclosiloxanes Comprehensive Polymer Science and Supplements. ,vol. 25, pp. 459- 523 ,(1989) , 10.1016/B978-0-08-096701-1.00140-3
Edwin L. Thomas, David J. Kinning, David B. Alward, Chris S. Henkee, Ordered packing arrangements of spherical micelles of diblock copolymers in two and three dimensions Macromolecules. ,vol. 20, pp. 2934- 2939 ,(1987) , 10.1021/MA00177A049
K. M. Hong, J. Noolandi, Theory of inhomogeneous multicomponent polymer systems Macromolecules. ,vol. 14, pp. 727- 736 ,(1981) , 10.1021/MA50004A051
N. Bloembergen, On the interaction of nuclear spins in a crystalline lattice Physica D: Nonlinear Phenomena. ,vol. 15, pp. 386- 426 ,(1949) , 10.1016/0031-8914(49)90114-7
U. Murschall, E. W. Fischer, Ch. Herkt-Maetzky, G. Fytas, Investigation of the mutual diffusion in compatible mixture of two homopolymers by photon correlation spectroscopy Journal of Polymer Science: Polymer Letters Edition. ,vol. 24, pp. 191- 197 ,(1986) , 10.1002/POL.1986.140240408
Edwin L. Thomas, David B. Alward, David J. Kinning, David C. Martin, Dale L. Handlin, Lewis J. Fetters, Ordered bicontinuous double-diamond structure of star block copolymers: a new equilibrium microdomain morphology Macromolecules. ,vol. 19, pp. 2197- 2202 ,(1986) , 10.1021/MA00162A016
Glenn H. Fredrickson, Eugene Helfand, Fluctuation effects in the theory of microphase separation in block copolymers The Journal of Chemical Physics. ,vol. 87, pp. 697- 705 ,(1987) , 10.1063/1.453566