Chalcogen adsorption and surface magnetism

作者: M Getzlaff , C Westphal , J Bansmann , G Schönhense

DOI: 10.1016/S0368-2048(00)00181-X

关键词:

摘要: Abstract Investigations concerning the electronic and magnetic properties of oxygen sulfur adsorbed on magnetized surfaces were carried out by means angle spin resolving photoelectron spectroscopy. Iron(110), a polycrystalline iron alloy, an amorphous metallic glass (Fe 79 B 16 Si 5 ) served as ferromagnetic substrates. Exchange splittings O 2p S 3p derived levels could be detected, demonstrating coupling between chemisorbate iron. This observation presents prerequisite for induced moment within adsorbate overlayer. For adsorbate-induced structure only in minority channel near Fermi level was observed which predicted theoretical calculations. feature is localized topmost layer.

参考文章(36)
A. Clarke, N. B. Brookes, P. D. Johnson, M. Weinert, B. Sinković, N. V. Smith, Spin-polarized photoemission studies of the adsorption of O and S on Fe(001) Physical Review B. ,vol. 41, pp. 9659- 9667 ,(1990) , 10.1103/PHYSREVB.41.9659
Giorgio Rossi, Giancarlo Panaccione, Fausto Sirotti, Effect of S segregation on the surface magnetism of Fe(100). Physical Review B. ,vol. 54, pp. 4080- 4086 ,(1996) , 10.1103/PHYSREVB.54.4080
J. J. Krebs, B. T. Jonker, G. A. Prinz, Magnetic and structural properties of Fe(100)/Ag(100) single‐crystal multilayer films with ultrathin Fe layers Journal of Applied Physics. ,vol. 63, pp. 3467- 3469 ,(1988) , 10.1063/1.340768
R. Allenspach, M. Taborelli, M. Landolt, Oxygen on Fe(100): An Initial-Oxidation Study by Spin-Polarized Auger Spectroscopy Physical Review Letters. ,vol. 55, pp. 2599- 2602 ,(1985) , 10.1103/PHYSREVLETT.55.2599
W. Schmitt, K.-P. Kämper, G. Güntherodt, Effect of adsorbates on the spin-polarized photoemission of itinerant ferromagnets Physical Review B. ,vol. 36, pp. 3763- 3768 ,(1987) , 10.1103/PHYSREVB.36.3763
Mathias Getzlaff, Joachim Bansmann, Gerd Schönhense, The electronic structure of benzene adsorbed on thin Fe(110) and Co(0001) films Surface Science. ,vol. 323, pp. 118- 128 ,(1995) , 10.1016/0039-6028(94)00641-5
B. Sinković, P. D. Johnson, N. B. Brookes, A. Clarke, N. V. Smith, Study of local magnetic properties of an adsorbate by spin-polarized Auger-electron spectroscopy Physical Review Letters. ,vol. 62, pp. 2740- 2743 ,(1989) , 10.1103/PHYSREVLETT.62.2740
M. Weinert, J. W. Davenport, Chemisorption of H on magnetic Ni(001). Physical Review Letters. ,vol. 54, pp. 1547- 1550 ,(1985) , 10.1103/PHYSREVLETT.54.1547
P. D. Johnson, A. Clarke, N. B. Brookes, S. L. Hulbert, B. Sinkovic, N. V. Smith, Exchange-split adsorbate bands: The role of substrate hybridization. Physical Review Letters. ,vol. 61, pp. 2257- 2260 ,(1988) , 10.1103/PHYSREVLETT.61.2257