Effect of pendant arm length and nitrogen donor disposition on the topology of luminescent cadmium phenylenedicarboxylate coordination polymers with bis(pyridylmethyl)piperazine co-ligands
作者： Karyn M. Blake , Gregory A. Farnum , Lindsey L. Johnston , Robert L. LaDuca
DOI: 10.1016/J.ICA.2009.09.043
关键词:
摘要: Abstract Hydrothermal synthesis has afforded divalent cadmium coordination polymers containing bis(pyridylmethyl)piperazine (bpmp) tethers and either phenylenediacetate (phda) or phenylenedipropionate (phdp) ligands. {[Cd(1,4-phda)(4-bpmp)]·1.5H2O}n (1) displays a (4,4)-grid layered structure based on 4-connected {Cd2O2} dimeric units. Extension of the pendant arms generated {[Cd(1,4-phdp)(H4-bpmp)](ClO4)·3.5H2O}n (2, phdp = phenylenedipropionate), which possesses rare (3,6) 2D trigonal lattice 6-connected dimers. Changing nitrogen donor atom disposition by using 3-bpmp as co-ligand yielded [Cd(1,4-phdp)(3-bpmp)(H2O)]n (3), crystallizes in 3-fold interpenetrated achiral diamondoid lattice. [Cd(1,3-phda)(4-bpmp)]n (4) adopts very similar to that 1. Complexes 1–4 undergo blue-violet luminescence upon exposure ultraviolet radiation.
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sci-hub.se 参考文章(63)
Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim, A homochiral metal-organic porous material for enantioselective separation and catalysis Nature. ,vol. 404, pp. 982- 986 ,(2000) , 10.1038/35010088
Hailian Li, Mohamed Eddaoudi, M. O'Keeffe, O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework Nature. ,vol. 402, pp. 276- 279 ,(1999) , 10.1038/46248
Shutao Wang, Yu Hou, Enbo Wang, Yangguang Li, Lin Xu, Jun Peng, Shuxia Liu, Changwen Hu, A novel organic-inorganic hybrid material with fluorescent emission: [Cd(PT)(H2O)]n (PT = phthalate) New Journal of Chemistry. ,vol. 27, pp. 1144- 1147 ,(2003) , 10.1039/B211358A
Yan Qi, Yun-Xia Che, Ji-Min Zheng, A zinc(II) coordination polymer constructed from mixed-ligand 1,2-bis(2-(1H-imidazol-1-yl)ethoxy)ethane and 1,4-benzenedicarboxylic acid CrystEngComm. ,vol. 10, pp. 1137- 1139 ,(2008) , 10.1039/B801387J
Shuangquan Zang, Yang Su, Yizhi Li, Zhaoping Ni, Qingjin Meng, Assemblies of a New Flexible Multicarboxylate Ligand and d10 Metal Centers toward the Construction of Homochiral Helical Coordination Polymers: Structures, Luminescence, and NLO-Active Properties Inorganic Chemistry. ,vol. 45, pp. 174- 180 ,(2006) , 10.1021/IC051502M
Jun Tao, Ming-Liang Tong, Jian-Xin Shi, Xiao-Ming Chen, Seik Weng Ng, Blue photoluminescent zinc coordination polymers with supertetranuclear cores Chemical Communications. pp. 2043- 2044 ,(2000) , 10.1039/B005753N
N. L. Rosi, Hydrogen Storage in Microporous Metal-Organic Frameworks Science. ,vol. 300, pp. 1127- 1129 ,(2003) , 10.1126/SCIENCE.1083440
Svetlana G. Baca, Manfred T. Reetz, Richard Goddard, Irina G. Filippova, Yurii A. Simonov, Maria Gdaniec, Nicolae Gerbeleu, Coordination polymers constructed from o-phthalic acid and diamines: Syntheses and crystal structures of the phthalate-imidazole complexes {[Cu(Pht)(Im)2] · 1.5H2O}n and [Co(Pht)(Im)2]n and their application in oxidation catalysis Polyhedron. ,vol. 25, pp. 1215- 1222 ,(2006) , 10.1016/J.POLY.2005.09.003
Lei Wang, Ming Yang, Guanghua Li, Zhan Shi, Shouhua Feng, Highly stable chiral cadmium 1,2,4-benzenetricarboxylate: synthesis, structure, and NLO and fluorescence properties. Inorganic Chemistry. ,vol. 45, pp. 2474- 2478 ,(2006) , 10.1021/IC051566X
David J. Tranchemontagne, José L. Mendoza-Cortés, Michael O’Keeffe, Omar M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal–organic frameworks Chemical Society Reviews. ,vol. 38, pp. 1257- 1283 ,(2009) , 10.1039/B817735J