Heterolytic fragmentation of deltaline, a norditerpenoid alkaloid
作者： Santosh K. Srivastava , Balawant S. Joshi , M.Gary Newton , Doowon Lee , S.William Pelletier
DOI: 10.1016/0040-4039(94)02300-Z
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摘要: Abstract The rearrangement product obtained by treatment of the norditerpenoid alkaloid deltaline ( 1 ) with SOCl 2 in moist benzene has been assigned structure 5 . This compound was also 10-chloro-10-deoxydeltaline 4 aqueous MeOH. However, when treated methanolic KOH, a novel rearranged pyrrolidine 8 obtained. Structures and for these heterolytic fragmentation products were established nmr spectroscopic data an X-ray crystal determination
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