Determination of specific heat in multi-component chalcogenide glasses of Se–Te–Sn–Pb system using modulated differential scanning calorimetry

作者: A. Sharma , H. Kumar , N. Mehta

DOI: 10.1016/J.MATLET.2012.07.013

关键词:

摘要: Abstract In the recent past, glass physicists have focused their attention on element lead as a modifier due to observation of carrier-type reversal in chalcogenide glasses for particular composition certain glassy systems after incorporation lead. Keeping this fact mind, some new quaternary been synthesized using Pb ternary Se78Te20Sn2 alloy parent glass. Specific heat studies made Se78−xTe20Sn2Pbx(0≤x≤6) alloys modulated differential scanning calorimetry (MDSC) technique. An extremely large increase specific values has observed at transition temperature. The dependence below temperature (Cpe) and (Cpg) also explained.

参考文章(23)
P. Ramanathan, K.R. Murali, Characteristics of slurry coated lead selenide films National Institute of Materials Physics. ,(2009)
M. Reading, A. Luget, R. Wilson, Modulated differential scanning calorimetry Thermochimica Acta. ,vol. 238, pp. 295- 307 ,(1994) , 10.1016/S0040-6031(94)85215-4
K. L. Bhatia, D. P. Gosain, G. Parthasarasthy, E. S. T. Gopal, A. K. Sharma, Structural properties of doped n-type amorphous (GeSe3.5)100−xBix Journal of Materials Science Letters. ,vol. 5, pp. 181- 182 ,(1986) , 10.1007/BF01672042
Pierre Lucas, Michelle A. Solis, David Le Coq, Christophe Juncker, Mark R. Riley, Jayne Collier, Dianne E. Boesewetter, Catherine Boussard-Plédel, Bruno Bureau, Infrared biosensors using hydrophobic chalcogenide fibers sensitized with live cells Sensors and Actuators B-chemical. ,vol. 119, pp. 355- 362 ,(2006) , 10.1016/J.SNB.2005.12.033
L Carpentier, O Bustin, M Descamps, Temperature-modulated differential scanning calorimetry as a specific heat spectroscopy Journal of Physics D. ,vol. 35, pp. 402- 408 ,(2002) , 10.1088/0022-3727/35/4/317
L. Kungumadevi, K. Rajasekar, A. Subbarayan, R. Sathyamoorthy, Structural and dc conduction studies on PbTe thin films Ionics. ,vol. 14, pp. 63- 67 ,(2008) , 10.1007/S11581-007-0145-4
P. Predeep, N.S. Saxena, A. Kumar, Crystallization and specific heat studies of Se100 − xSbx (x = 0, 2 and 4) glass Journal of Physics and Chemistry of Solids. ,vol. 58, pp. 385- 389 ,(1997) , 10.1016/S0022-3697(96)00148-5
Shipra Saraswat, S. S. S. Kushwaha, Specific heat studies in a-Se and a-Se90M10 (M = In, Sb, Te) alloys Journal of Thermal Analysis and Calorimetry. ,vol. 96, pp. 923- 927 ,(2009) , 10.1007/S10973-009-0065-9
C.J. Baddiley, J. Ring, A wide field infrared photometer Infrared Physics. ,vol. 17, pp. 405- 413 ,(1977) , 10.1016/0020-0891(77)90042-2
P K Nair, M T S Nair, PbS solar control coatings: safety, cost and optimisation Journal of Physics D. ,vol. 23, pp. 150- 155 ,(1990) , 10.1088/0022-3727/23/2/004