Adsorption of hydrogen on clean and potassium modified low index copper surfaces: Cu(100) and Cu(110)

作者: L. Thomsen , J. Onsgaard , P. J. Godowski , P. Møller , S. V. Hoffmann

DOI: 10.1116/1.1359552

关键词:

摘要: The adsorption of atomic hydrogen has been studied on clean and potassium modified Cu(110) Cu(100) surfaces. Two induced states in the valence band have found surface, an α state receding subsurface a β surface crystal. Upon annealing, both diffuses to desorbs at 330 K, into bulk. states, αK βK, also observed surfaces, with assigned potassium-hydrogen bond βK Cu–hydrogen bond. is significantly more reactive than surface.

参考文章(17)
M. Christiansen, E.V. Thomsen, J. Onsgaard, Coadsorption of K and CO on Cu(110) Surface Science. ,vol. 261, pp. 179- 190 ,(1992) , 10.1016/0039-6028(92)90230-4
So/ren V. Christensen, Jesper Nerlov, P. Jan Godowski, Jens Onsgaard, Photoemission and high resolution electron energy loss spectroscopy study of CO/K/Cu(110) Journal of Chemical Physics. ,vol. 104, pp. 9613- 9619 ,(1996) , 10.1063/1.471702
Felix Greuter, E. Ward Plummer, Chemisorption of atomic hydrogen on Cu(111) Solid State Communications. ,vol. 48, pp. 37- 41 ,(1983) , 10.1016/0038-1098(83)90178-3
P.T. Sprunger, E.W. Plummer, The interaction of hydrogen with simple metal surfaces Surface Science. pp. 118- 123 ,(1994) , 10.1016/0039-6028(94)90380-8
K. H. Rieder, W. Stocker, Hydrogen-induced subsurface reconstruction of Cu(110). Physical Review Letters. ,vol. 57, pp. 2548- 2551 ,(1986) , 10.1103/PHYSREVLETT.57.2548
A. P. Baddorf, I.‐W. Lyo, E. W. Plummer, H. L. Davis, Removal of surface relaxation of Cu(110) by hydrogen adsorption Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. ,vol. 5, pp. 782- 786 ,(1987) , 10.1116/1.574344
K. Christmann, Interaction of hydrogen with solid surfaces Surface Science Reports. ,vol. 9, pp. 1- 163 ,(1988) , 10.1016/0167-5729(88)90009-X