Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three‐Shell 145‐Atom Metal‐Core Geometry of Pseudo Icosahedral Symmetry
作者： Nguyet T. Tran , Douglas R. Powell , Lawrence F. Dahl
DOI: 10.1002/1521-3773(20001117)39:22<4121::AID-ANIE4121>3.0.CO;2-A
关键词:
摘要: The layer‐by‐layer growth pattern of the ligated capped 3‐shell Pd145 core of the nanosized cluster Pd145 (CO) x (PEt3) 30 presumably involves an energetic compromise between the maximization of atom connectivities (resulting in the lowest surface Pd coordination number being seven) and the minimization of icosahedral strain energy.
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