Wavelength dependence of photocatalytic cyclohexane dehydrogenation by carbonyl- and thiocarbonyl-(chloro)phosphine rhodium(I) complexes
作者： Aki Iwamoto , Hiroaki Itagaki , Yasukazu Saito
DOI: 10.1039/DT9910001093
关键词:
摘要: Photocatalytic dehydrogenation of cyclohexane using [RhCl(CS)(PPh3)2] was closely related to photodissociation the CS ligand, where effective absorption band not lowest energy but second lowest, in contrast CO analogue. The estimated turnover number [RhCl(PPh3)2] cycle 3.8 on assumption that is photodecomposed irreversibly. wavelength dependence photocatalysis by these complexes well interpreted terms molecular-orbital levels and orbital interactions.
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