Alkene and dihydrogen formation by catalytic dehydrogenation of alkane with RhCl(pr3)2 photogenerated from rhcl(co)(pr3)2

作者: Kotohiro Nomura , Yasukazu Saito

DOI: 10.1016/0304-5102(89)80138-5

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摘要: Abstract Alkene and dihydrogen formation by photocatalytic dehydrogenation of alkanes using RhCl(CO)(PR3)2 proceeded with high turnover frequencies, amounting to 1404 h−1 for nonane at 132 °C (PR3 = PMe3). The activity order PPh3

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