Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate : Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes
作者： O. V. Loseva , T. A. Rodina , O. N. Antzutkin , A. V. Ivanov
DOI: 10.1134/S1070363218120149
关键词:
摘要: The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl studied. gold from the forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido comprising three isomeric cations unsymmetrical hexachlorodimercurate anion. structural organization thermal behavior resulting compounds
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