Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.
作者： Domingo García-Cuadrado , Ataualpa A. C. Braga , Feliu Maseras , Antonio M. Echavarren
DOI: 10.1021/JA056165V
关键词:
摘要: Under the usual conditions, Pd-catalyzed arylation does not involve an electrophilic aromatic substitution reaction. On basis of DFT calculations, we propose a mechanism for that involves proton abstraction by carbonate or related ligand and provides satisfactory explanation experimental data.
acs.org
unirioja.es
sci-hub.se 参考文章(0)