Application of monodentate secondary phosphine oxides, a new class of chiral ligands, in Ir(I)-catalyzed asymmetric imine hydrogenation

作者: Xiao-bin Jiang , Adriaan J. Minnaard , Bart Hessen , Ben L. Feringa , Alexander L. L. Duchateau

DOI: 10.1021/OL034282U

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摘要: … It is conceivable that the acidic proton of SPOs has an accelerating effect upon the transition metal-catalyzed hydrogenation of imines. We thus tested the hydrogenation of a range of …

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