Factors influencing the glass transition of DGEBA-anhydride epoxy resins
作者： G.C. Stevens , M.J. Richardson
DOI: 10.1016/0032-3861(83)90203-3
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摘要: Abstract A number of chemical and physical factors influence the glass transition behaviour anhydride-cured diglycidyl ether bisphenol (DGEBA) type epoxy resins. Several these were investigated using differential scanning calorimetry to assess nature transition, temperature glass- liquid-phase specific heats. The molecular weight functionality, cooling rate silica fillers for unreacted prepolymers. Two systems also considered cure with without effect phase separation investigated.
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sci-hub.se 参考文章(17)
W. Fisch, W. Hofmann, Über den Härtungsmechanismus der äthoxylinharze Journal of Polymer Science Part A. ,vol. 12, pp. 497- 502 ,(1954) , 10.1002/POL.1954.120120141
Jose V. Aleman, Glass transitions of epoxide prepolymers Journal of Polymer Science Part A. ,vol. 18, pp. 2561- 2565 ,(1980) , 10.1002/POL.1980.170180814
Thomas G. Fox, Paul J. Flory, Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight Journal of Applied Physics. ,vol. 21, pp. 581- 591 ,(1950) , 10.1063/1.1699711
Paul Peyser, Willard D. Bascom, Effect of filler and cooling rate on the glass transition of polymers Journal of Macromolecular Science, Part B. ,vol. 13, pp. 597- 610 ,(1977) , 10.1080/00222347708212211
H. Batzer, S. A. Zahir, Studies in the molecular weight distribution of epoxide resins. I. Gel permeation chromatography of epoxide resins Journal of Applied Polymer Science. ,vol. 19, pp. 585- 600 ,(1975) , 10.1002/APP.1975.070190220
Gary C. Stevens, Cure kinetics of a high epoxide/hydroxyl group‐ratio bisphenol a epoxy resin—anhydride system by infrared absorption spectroscopy Journal of Applied Polymer Science. ,vol. 26, pp. 4279- 4297 ,(1981) , 10.1002/APP.1981.070261225
F. Rietsch, D. Daveloose, D. Froelich, Glass transition temperature of ideal polymeric networks Polymer. ,vol. 17, pp. 859- 863 ,(1976) , 10.1016/0032-3861(76)90251-2
G.C. Stevens, J.V. Champion, P. Liddell, A. Dandridge, Light scattering studies of DGEBA-anhydride epoxy resin heterogeneity Chemical Physics Letters. ,vol. 71, pp. 104- 109 ,(1980) , 10.1016/0009-2614(80)85299-7
M. J. Richardson, Precision differential calorimetry and the heat of fusion of polyethylene Journal of Polymer Science Part C: Polymer Symposia. ,vol. 38, pp. 251- 259 ,(1972) , 10.1002/POLC.5070380120
M.J. Richardson, N.G. Savill, Derivation of accurate glass transition temperatures by differential scanning calorimetry Polymer. ,vol. 16, pp. 753- 757 ,(1975) , 10.1016/0032-3861(75)90194-9