Quantum theory of infrared-reflection spectroscopy from adsorbate-covered metal surfaces in the anomalous-skin-effect frequency region.
作者： A. I. Volokitin , B. N. J. Persson
关键词:
摘要: A fully quantum-mechanical theory of infrared-reflection spectroscopy from adsorbate-covered metal surfaces is presented. In contrast to our earlier semiclassical [B. N. J. Persson and A. I. Volokitin, Surf. Sci. 310, 314 (1994)], which valid only for parallel vibrational modes atomic adsorbates, the present applicable arbitrary dipole-forbidden modes. It shown that a with broad conduction band, asymmetry line shape adsorbate determined essentially by nonlocal optics effects, negligible contribution nonadiabaticity. The in good agreement experimental data.
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