Nanostructuring Platinum Nanoparticles on Multilayered Graphene Petal Nanosheets for Electrochemical Biosensing

作者: Jonathan C. Claussen , Anurag Kumar , David B. Jaroch , M. Haseeb Khawaja , Allison B. Hibbard

DOI: 10.1002/ADFM.201200551

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摘要: Hybridization of nanoscale metals and carbon nanotubes into composite nanomaterials has produced some the best-performing sensors to date. The challenge remains develop scalable nanofabrication methods that are amenable development with broad sensing ranges. A nanostructured biosensor based on multilayered graphene petal nanosheets (MGPNs), Pt nanoparticles, a biorecognition element (glucose oxidase) is presented. combination zero-dimensional nanoparticles two-dimensional support arrayed in third dimension creates sensor platform exceptional characteristics. versatility demonstrated by altering performance (i.e., sensitivity, detection limit, linear range) through changing size, density, morphology electrodeposited MGPNs. This work enables robust design demonstrates enhanced glucose sensitivity (0.3 µM 0.01–50 mM range), long stable shelf-life (>1 month), high selectivity over electroactive, interfering species commonly found human serum samples.

参考文章(66)
Sang Hoon Joo, Seong Jae Choi, Ilwhan Oh, Juhyoun Kwak, Zheng Liu, Osamu Terasaki, Ryong Ryoo, Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles Nature. ,vol. 412, pp. 169- 172 ,(2001) , 10.1038/35084046
Jonathan C. Claussen, James B. Hengenius, Monique M. Wickner, Timothy S. Fisher, David M. Umulis, D. Marshall Porterfield, Effects of Carbon Nanotube-Tethered Nanosphere Density on Amperometric Biosensing: Simulation and Experiment Journal of Physical Chemistry C. ,vol. 115, pp. 20896- 20904 ,(2011) , 10.1021/JP205569Z
Qiong Zeng, Jinsheng Cheng, Longhua Tang, Xiaofei Liu, Yanzhe Liu, Jinghong Li, Jianhui Jiang, Self‐Assembled Graphene–Enzyme Hierarchical Nanostructures for Electrochemical Biosensing Advanced Functional Materials. ,vol. 20, pp. 3366- 3372 ,(2010) , 10.1002/ADFM.201000540
Nai Gui Shang, Pagona Papakonstantinou, Martin McMullan, Ming Chu, Artemis Stamboulis, Alessandro Potenza, Sarnjeet S. Dhesi, Helder Marchetto, Catalyst-Free Efficient Growth, Orientation and Biosensing Properties of Multilayer Graphene Nanoflake Films with Sharp Edge Planes** Advanced Functional Materials. ,vol. 18, pp. 3506- 3514 ,(2008) , 10.1002/ADFM.200800951
Markus Dankerl, Moritz V. Hauf, Andreas Lippert, Lucas H. Hess, Stefan Birner, Ian D. Sharp, Ather Mahmood, Pierre Mallet, Jean-Yves Veuillen, Martin Stutzmann, Jose A. Garrido, Graphene Solution‐Gated Field‐Effect Transistor Array for Sensing Applications Advanced Functional Materials. ,vol. 20, pp. 3117- 3124 ,(2010) , 10.1002/ADFM.201000724
Leyla Soleymani, Zhichao Fang, Edward H. Sargent, Shana O. Kelley, Programming the detection limits of biosensors through controlled nanostructuring Nature Nanotechnology. ,vol. 4, pp. 844- 848 ,(2009) , 10.1038/NNANO.2009.276
Joseph Wang, Nanomaterial-based electrochemical biosensors Analyst. ,vol. 130, pp. 421- 426 ,(2005) , 10.1039/B414248A
Hongmei Zhang, Fengxing Jiang, Rong Zhou, Yukou Du, Ping Yang, Chuanyi Wang, Jingkun Xu, Effect of deposition potential on the structure and electrocatalytic behavior of Pt micro/nanoparticles International Journal of Hydrogen Energy. ,vol. 36, pp. 15052- 15059 ,(2011) , 10.1016/J.IJHYDENE.2011.08.072
Y LANYON, D ARRIGAN, Recessed nanoband electrodes fabricated by focused ion beam milling Sensors and Actuators B-chemical. ,vol. 121, pp. 341- 347 ,(2007) , 10.1016/J.SNB.2006.11.029