Unusual metal-organic frameworks built from 2D layers through Cl⋯Cl contacts and hydrogen bonds
作者： Hai-Bin Zhu , Zhao-Lian Chu , Da-Hua Hu , Wei Huang , Shao-Hua Gou
DOI: 10.1016/J.INOCHE.2006.11.015
关键词:
摘要: Abstract Unusual metal-organic frameworks [M(dtcp)2](SCN)2 [M = Zn, Mn; dtcp = 2,6-di(1,2,4-triazol-1-ylmethyl)-4-chlorophenol] are composed of 2D rhombus-type grid networks associated mutually by remarkable Cl⋯Cl contacts and hydrogen bonds (C–H⋯N C–H⋯S). Both thermogravimetric analysis photoluminescence measurements performed as well to characterize these supramolecular frameworks.
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