Formation of secondary ozonides in the gas-phase ozonolysis of simple alkenes

作者: Peter Neeb , Osamu Horie , Geert K Moortgat

DOI: 10.1016/S0040-4039(97)82946-2

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摘要: Secondary propene ozonide and isobutene were formed in the gas-phase ozonolysis of ethene with added acetaldehyde acetone, respectively. Combined formation hydroperoxymethyl formate methoxymethyl hydroperoxide ethene-ozone reaction system presence HCOOH CH3OH, respectively, secondary ozonides reveals a close similarity between liquid-phase alkenes.

参考文章(15)
Peter Neeb, Osamu Horie, Geert K. Moortgat, The nature of the transitory product in the gas-phase ozonolysis of ethene Chemical Physics Letters. ,vol. 246, pp. 150- 156 ,(1995) , 10.1016/0009-2614(95)01073-I
H. Niki, P.D. Maker, C.M. Savage, L.P. Breitenbach, Fourier transform IR spectroscopic observation of propylene ozonide in the gas phase reaction of ozone—cis-2-butene—formaldehyde Chemical Physics Letters. ,vol. 46, pp. 327- 330 ,(1977) , 10.1016/0009-2614(77)85273-1
Radek Fajgar, Josef Vítek, Yehuda Haas, Josef Pola, Observation of secondary 2-butene ozonide in the ozonation of trans-2-butene in the gas phase Tetrahedron Letters. ,vol. 37, pp. 3391- 3394 ,(1996) , 10.1016/0040-4039(96)00554-0
S. Hatakeyama, H. Akimoto, Reactions of criegee intermediates in the gas phase Research on Chemical Intermediates. ,vol. 20, pp. 503- 524 ,(1994) , 10.1163/156856794X00432
Roland Gutbrod, Ralph N. Schindler, Elfi Kraka, Dieter Cremer, Formation of OH radicals in the gas phase ozonolysis of alkenes: the unexpected role of carbonyl oxides Chemical Physics Letters. ,vol. 252, pp. 221- 229 ,(1996) , 10.1016/0009-2614(96)00126-1
O. Horie, G.K. Moortgat, A new transitory product in the ozonolysis of trans-2-butene at atmospheric pressure Chemical Physics Letters. ,vol. 156, pp. 39- 46 ,(1989) , 10.1016/0009-2614(89)87077-0
H. Niki, P. D. Maker, C. M. Savage, L. P. Breitenbach, M. D. Hurley, FTIR spectroscopic study of the mechanism for the gas-phase reaction between ozone and tetramethylethylene The Journal of Physical Chemistry. ,vol. 91, pp. 941- 946 ,(1987) , 10.1021/J100288A035
Rudolf Criegee, Mechanism of Ozonolysis Angewandte Chemie. ,vol. 14, pp. 745- 752 ,(1975) , 10.1002/ANIE.197507451
Title. Philip S. Bailey, Philip S. Bailey, Ozonation in Organic Chemistry ,(1978)
Roger Atkinson, Gas-phase tropospheric chemistry of organic compounds: A review Atmospheric Environment. ,vol. 24, pp. 1- 41 ,(1990) , 10.1016/0960-1686(90)90438-S