The effect of a magnetic field on the high-spin α low-spin transition in [Fe(phen)2(NCS)2]

作者: Y. Qi , E.W. Müller , H. Spiering , P. Gütlich

DOI: 10.1016/0009-2614(83)87521-6

关键词:

摘要: Abstract The transition temperature of [Fe(phen) 2 (NCS) ] measured by susceptibility measurements in an applied field 1 T shifts −0.11 − 0.04 K when the is increased to 5.5 T. This shift predicted on basis known magnetic and specific heat data.

参考文章(5)
Takeshi Kambara, The Effect of Iron Concentration on the High-Spin\(\rightleftarrows\)Low-Spin Transitions in Iron Compounds Journal of the Physical Society of Japan. ,vol. 49, pp. 1806- 1811 ,(1980) , 10.1143/JPSJ.49.1806
E.W. Müller, H. Spiering, P. Gütlich, Spin transition in [Fe(phen)2(NCS)2] and [Fe(bipy)2(NCS)2]: Hysteresis and effect of crystal quality Chemical Physics Letters. ,vol. 93, pp. 567- 571 ,(1982) , 10.1016/0009-2614(82)83731-7
Philipp Gütlich, Spin crossover in iron(II)-complexes Springer, Berlin, Heidelberg. pp. 83- 195 ,(1981) , 10.1007/BFB0111269