Tetracarbonylwolfram-komplexe mit zwei unterschiedlichen donorliganden : II. Photochemische ligandensubstitution an trans-bis(phosphin)-komplexen
作者： Wolfdieter A. Schenk
DOI: 10.1016/S0022-328X(00)83487-7
关键词:
摘要: Abstract Tungsten (0) complexes trans -LL′W(CO) 4 (L ≠ L′: i-Pr 3 P, Ph (Me 2 N) (i-PrO) P (PhO) P) fall into two categories with respect to their photochemistry. Compounds of type A, which contain at least one strongly donating phosphine ligand, lose the axial phosphines upon irradiation. Of different phosphines, is always lost preferentially, photochemical lability increasing in series P. B, weakly ligands only, radial carbonyl groups These results are explained terms ligand field theory and Vanquickenborne's labilisation model.
elsevier.com
sci-hub.se 参考文章(20)
Wolfdieter A. Schenk, Substituierte halogenocarbonylmetallate des chroms, molybdäns und wolframs : III. Ligandensubstitution an halogenocarbonylmetallaten der VI. Nebengruppe Journal of Organometallic Chemistry. ,vol. 179, pp. 253- 261 ,(1979) , 10.1016/S0022-328X(00)91743-1
Mark Wrighton, Photochemistry of metal carbonyls Chemical Reviews. ,vol. 74, pp. 401- 430 ,(1974) , 10.1021/CR60290A001
Harry B. Gray, Mark Wrighton, G. S. Hammond, Emission from tungsten carbonyl complexes Journal of the American Chemical Society. ,vol. 93, pp. 4336- 4337 ,(1971) , 10.1021/JA00746A064
Donald J. Darensbourg, Mark A. Murphy, The solution photosubstitution chemistry of triphenylphosphine derivatives of molybdenum hexacarbonyl Journal of the American Chemical Society. ,vol. 100, pp. 463- 468 ,(1978) , 10.1021/JA00470A016
Wolfdieter A. Schenk, Substituierte halog nocarbonyl-metallate des molybd/:ans und wolframs Journal of Organometallic Chemistry. ,vol. 117, ,(1976) , 10.1016/S0022-328X(00)87221-6
Nancy A. Beach, Harry B. Gray, Electronic structures of metal hexacarbonyls Journal of the American Chemical Society. ,vol. 90, pp. 5713- 5721 ,(1968) , 10.1021/JA01023A011
Jeffrey I. Zink, Model for predicting the photoreactions and relative quantum yields of transition metal and organometallic complexes. II. Cobalt(III) and rhodium(III) Inorganic Chemistry. ,vol. 12, pp. 1018- 1024 ,(1973) , 10.1021/IC50123A010
R. Marc. Dahlgren, Jeffrey I. Zink, Ligand substitution photochemistry of monosubstituted derivatives of tungsten hexacarbonyl Inorganic Chemistry. ,vol. 16, pp. 3154- 3161 ,(1977) , 10.1021/IC50178A034
G. Boxhoorn, A. Oskam, Photochemistry of W(CO)5PCl3 in an Ar matrix at 10 K Inorganica Chimica Acta. ,vol. 29, pp. 243- 248 ,(1978) , 10.1016/S0020-1693(00)89655-3
Mark. Wrighton, Photoreactions of aminepentacarbonylmolybdenum(0) and -tungsten(0) Inorganic Chemistry. ,vol. 13, pp. 905- 909 ,(1974) , 10.1021/IC50134A030