Organic Molecules on Noble Metal Surfaces: The Role of the Interface

作者: Maddalena Pedio , Cinzia Cepek , Roberto Felici

DOI: 10.5772/34551

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摘要: Among the new developments in use of noble metals, organic-inorganic systems formed by Self Assembled Molecular (SAM) layering on metal surfaces represent a main topic. In this chapter we discuss complementary surface science techniques Applied to these sysems. Our aim is give an overview our recent case studies organic molecular layers interacting with surfaces. Functionalized assembled films are important many application fields, ranging from sensors and photovoltaic cells nanostructured devices. microelectronics adsorbed molecules subject intensive investigation, due fundamental interest interfacial coordination chemistry its potential applications. Physical details morphology, together grain size, orientation film concentration defects, play crucial role device performances, since they determine carrier injection properties.

参考文章(69)
Stefan Hüfner, Photoelectron Spectroscopy Springer Series in Solid-State Sciences. ,(1996) , 10.1007/978-3-662-03209-1
M.A. Van Hove, R.J. Koestner, P.C. Stair, J.P. Bibérian, L.L. Kesmodel, I. BartoŠ, G.A. Somorjai, The surface reconstructions of the (100) crystal faces of iridium, platinum and gold. I. Experimental observations and possible structural models Surface Science. ,vol. 103, pp. 189- 217 ,(1981) , 10.1016/0039-6028(81)90107-2
Gregor Bavdek, Albano Cossaro, Dean Cvetko, Cristina Africh, Cecilia Blasetti, Friedrich Esch, Alberto Morgante, Luca Floreano, Pentacene nanorails on Au(110). Langmuir. ,vol. 24, pp. 767- 772 ,(2008) , 10.1021/LA702004Z
M. Eremtchenko, R. Temirov, D. Bauer, J. A. Schaefer, F. S. Tautz, Formation of molecular order on a disordered interface layer : Pentacene/Ag(111) Physical Review B. ,vol. 72, pp. 115430- ,(2005) , 10.1103/PHYSREVB.72.115430
A. R. Sandy, S. G. J. Mochrie, D. M. Zehner, K. G. Huang, Doon Gibbs, Structure and phases of the Au(111) surface: X-ray-scattering measurements Physical Review B. ,vol. 43, pp. 4667- 4687 ,(1991) , 10.1103/PHYSREVB.43.4667
Hong Li, Yiqun Duan, Veaceslav Coropceanu, Jean-Luc Bredas, Electronic structure of the pentacene–gold interface: A density-functional theory study Organic Electronics. ,vol. 10, pp. 1571- 1578 ,(2009) , 10.1016/J.ORGEL.2009.09.003
C. J. Fall, N. Binggeli, A. Baldereschi, Work-function anisotropy in noble metals: Contributions from d states and effects of the surface atomic structure Physical Review B. ,vol. 61, pp. 8489- 8495 ,(2000) , 10.1103/PHYSREVB.61.8489
M. Pedio, R. Felici, X. Torrelles, P. Rudolf, M. Capozi, J. Rius, S. Ferrer, Study of C60/Au(110)-p(6 × 5) Reconstruction from In-Plane X-Ray Diffraction Data Physical Review Letters. ,vol. 85, pp. 1040- 1043 ,(2000) , 10.1103/PHYSREVLETT.85.1040
Flemming Besenbacher, Scanning tunnelling microscopy studies of metal surfaces Reports on Progress in Physics. ,vol. 59, pp. 1737- 1802 ,(1996) , 10.1088/0034-4885/59/12/004