Phosphate Ca1/4Sr1/4Zr2(PO4)3 of the NaZr2(PO4)3 structure type: Synthesis of a dense ceramic material and its radiation testing
作者： A.I. Orlova , V.Yu. Volgutov , D.A. Mikhailov , D.M. Bykov , V.A. Skuratov
DOI: 10.1016/J.JNUCMAT.2013.11.025
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摘要: Abstract The powder of phosphate Ca 1/4 Sr Zr 2 (PO 4 ) 3 was synthesized by sol–gel processes in the presence citric acid and ethylene glycol. Ceramic samples were prepared from this Spark Plasma Sintering (SPS), their relative densities found to be 99.5 ± 0.3% after isothermal treatment at 860 °С for 3 min. Sintered disc-shaped ceramic ( d = 10 mm, h = 4 mm) bombarded 300 K 167 MeV Xe 26+ ions with fluences ranging 6 ⋅ 10 10 1 ⋅ 10 13 ions/cm . It that exposure highest fluence (10 ion/cm led a complete amorphization irradiated layer. observed phase transition is ascribed formation amorphous latent tracks via dense electronic excitations. Postradiation heat revealed transformation metamict crystalline form took place annealing T = 200, 300, 400, 500, 600 800 °С t = 3, 13, 11, 5, 17 15 h, respectively.
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sci-hub.se 参考文章(37)
Xiaoxiong Xu, Zhaoyin Wen, Xuelin Yang, Lidong Chen, Dense nanostructured solid electrolyte with high Li-ion conductivity by spark plasma sintering technique Materials Research Bulletin. ,vol. 43, pp. 2334- 2341 ,(2008) , 10.1016/J.MATERRESBULL.2007.08.007
Albina I Orlova, Ilya G Trubach, Victoria S Kurazhkovskaya, Pilar Pertierra, Miguel A Salvadó, Santiago Garcı́a-Granda, Sergei A Khainakov, José R Garcı́a, Synthesis, characterization, and structural study of K2FeZrP3O12 with the langbeinite structure Journal of Solid State Chemistry. ,vol. 173, pp. 314- 318 ,(2003) , 10.1016/S0022-4596(03)00101-4
Niloy Chakraborty, Werner Ficher, Amit Das Gupta, Debabrata Basu, Performance of conventional CSZP-based ceramic coating on oxidation of carbon–carbon composites Surface & Coatings Technology. ,vol. 201, pp. 1152- 1159 ,(2006) , 10.1016/J.SURFCOAT.2006.01.049
Niloy Chakraborty, Debabrata Basu, Werner Fischer, Thermal expansion of Ca1−xSrxZr4(PO4)6 ceramics Journal of The European Ceramic Society. ,vol. 25, pp. 1885- 1893 ,(2005) , 10.1016/J.JEURCERAMSOC.2004.06.019
N. Clavier, N. Dacheux, R. Podor, Synthesis, Characterization, Sintering, and Leaching of β-TUPD/Monazite Radwaste Matrices Inorganic Chemistry. ,vol. 45, pp. 220- 229 ,(2006) , 10.1021/IC051607P
C CHANG, S HONG, H PARK, Spark plasma sintering of Al substituted LiHf2(PO4)3 solid electrolytes Solid State Ionics. ,vol. 176, pp. 2583- 2587 ,(2005) , 10.1016/J.SSI.2005.07.010
A. I. Orlova, M. P. Orlova, E. M. Solov’eva, E. E. Loginova, V. T. Demarin, G. N. Kazantsev, S. G. Samoilov, S. V. Stefanovskii, Lanthanides in phosphates with the structure of whitlockite mineral [analog of β-Ca3(PO4)2] Radiochemistry. ,vol. 48, pp. 561- 567 ,(2006) , 10.1134/S1066362206060038
B.E. Scheetz, D.K. Agrawal, E. Breval, R. Roy, Sodium zirconium phosphate (NZP) as a host structure for nuclear waste immobilization: A review Waste Management. ,vol. 14, pp. 489- 505 ,(1994) , 10.1016/0956-053X(94)90133-3
Anne Guesdon, Jackie Provost, Bernard Raveau, New thorium and uranium monophosphates in the KTh2(PO4)3 family: structure and cationic non-stoichiometry Journal of Materials Chemistry. ,vol. 9, pp. 2583- 2587 ,(1999) , 10.1039/A904121D
A. I. Orlova, A. K. Koryttseva, A. E. Kanunov, V. N. Chuvil’deev, A. V. Moskvicheva, N. V. Sakharov, M. S. Boldin, A. V. Nokhrin, Fabrication of NaZr 2 (PO 4 ) 3 -type ceramic materials by spark plasma sintering Inorganic Materials. ,vol. 48, pp. 313- 317 ,(2012) , 10.1134/S002016851202015X