One-pot synthesis of functional two-dimensional graphene/SnO2 composite nanosheets as a building block for self-assembly and an enhancing nanomaterial for biosensing

作者: Chengzhou Zhu , Youxing Fang , Dan Wen , Shaojun Dong

DOI: 10.1039/C1JM11612F

关键词:

摘要: A one-step approach to synthesize functional two-dimensional graphene/SnO2 composite nanosheets (GSCN) is reported. It should be noted that SnCl2 not only a reducing agent for graphene oxide (GO), but also precursor of SnO2. On the other hand, polyelectrolyte poly(diallyldimethylammonium chloride) (PDDA) was introduced simultaneously in preparation, endow it with an ideal self-assembly building block. Through electrostatic interaction, general method has been developed preparation ternary GSCN/nanoparticles (GSCN/NPs) hybrid structures high-density noble metal NPs. Prominent examples including Au, Pt and Au@Pt NPs could loaded on surface GSCN. Furthermore, we employed supported GSCN as electrochemical material nonenzymatic glucose detection, which exhibited good electrocatalytic activity.

参考文章(66)
Shaojun Guo, Liang Wang, Shaojun Dong, Erkang Wang, A Novel Urchinlike Gold/Platinum Hybrid Nanocatalyst with Controlled Size Journal of Physical Chemistry C. ,vol. 112, pp. 13510- 13515 ,(2008) , 10.1021/JP804347Q
C. Nethravathi, T. Nisha, N. Ravishankar, C. Shivakumara, M. Rajamathi, Graphene–nanocrystalline metal sulphide composites produced by a one-pot reaction starting from graphite oxide Carbon. ,vol. 47, pp. 2054- 2059 ,(2009) , 10.1016/J.CARBON.2009.03.055
Qiyuan He, Herry Gunadi Sudibya, Zongyou Yin, Shixin Wu, Hai Li, Freddy Boey, Wei Huang, Peng Chen, Hua Zhang, Centimeter-Long and Large-Scale Micropatterns of Reduced Graphene Oxide Films: Fabrication and Sensing Applications ACS Nano. ,vol. 4, pp. 3201- 3208 ,(2010) , 10.1021/NN100780V
Chengzhou Zhu, Shaojun Guo, Ping Wang, Li Xing, Youxing Fang, Yueming Zhai, Shaojun Dong, One-pot, water-phase approach to high-quality graphene/TiO2 composite nanosheets Chemical Communications. ,vol. 46, pp. 7148- 7150 ,(2010) , 10.1039/C0CC01459A
Hao Zhang, Xiaojun Lv, Yueming Li, Ying Wang, Jinghong Li, P25-Graphene Composite as a High Performance Photocatalyst ACS Nano. ,vol. 4, pp. 380- 386 ,(2010) , 10.1021/NN901221K
Jintao Zhang, Zhigang Xiong, X. S. Zhao, Graphene–metal–oxide composites for the degradation of dyes under visible light irradiation Journal of Materials Chemistry. ,vol. 21, pp. 3634- 3640 ,(2011) , 10.1039/C0JM03827J
Peng Guo, Huaihe Song, Xiaohong Chen, Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries Electrochemistry Communications. ,vol. 11, pp. 1320- 1324 ,(2009) , 10.1016/J.ELECOM.2009.04.036
Ling Meng, Juan Jin, Gaixiu Yang, Tianhong Lu, Hui Zhang, Chenxin Cai, Nonenzymatic electrochemical detection of glucose based on palladium-single-walled carbon nanotube hybrid nanostructures. Analytical Chemistry. ,vol. 81, pp. 7271- 7280 ,(2009) , 10.1021/AC901005P