Nickel-aluminum layered double hydroxide as a nanosorbent for selective solid-phase extraction and spectrofluorometric determination of salicylic acid in pharmaceutical and biological samples.
作者： H. Abdolmohammad-Zadeh , S. Kohansal , G.H. Sadeghi
DOI: 10.1016/J.TALANTA.2011.01.026
关键词:
摘要: The nickel-aluminum layered double hydroxide (Ni-Al LDH) was synthesized by a simple co-precipitation method and used as solid-phase extraction (SPE) sorbent for separation pre-concentration of trace levels salicylic acid (SA) from aqueous solutions. Extraction analyte is based on the adsorption salicylate ions Ni-Al (NO(3)(-)) LDH and/or their exchanging with interlayer NO(3)(-) ions. retained stripped 3 mol L(-1) NaOH solution its concentration subsequently determined spectrofluorometrically at λ(em)=400 nm excitation λ(ex)=270 nm. Various parameters affecting efficiency SA LDH, such pH, amount nano-sorbent, sample loading flow rate, elution conditions, volume matrix effects were investigated. In optimum experimental limit detection (3s) enrichment factor 0.12 μg 40, respectively. relative standard deviation (RSD) six replicate determinations 10 2.3%. calibration graph using system linear in range 0.3-45 correlation coefficient 0.9985. optimized successfully applied to determination blood serum, willow leaf aspirin tablet.
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sci-hub.se 参考文章(29)
C. Forano, T. Hibino, F. Leroux, C. Taviot-Guého, Chapter 13.1 Layered Double Hydroxides Developments in Clay Science. ,vol. 1, pp. 1021- 1095 ,(2006) , 10.1016/S1572-4352(05)01039-1
Scott M. Auerbach, Prabir K. Dutta, Kathleen A. Carrado, Handbook of Layered Materials ,(2004)
Vicente Rives, Layered double hydroxides : present and future Nova Science Publishers. ,(2001)
Mas Verónica, Baronetti Graciela, Amadeo Norma, Laborde Miguel, Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor: Kinetic study Chemical Engineering Journal. ,vol. 138, pp. 602- 607 ,(2008) , 10.1016/J.CEJ.2007.08.035
Jian-feng Yang, Zhen-tao Zhou, Use of spray technique to prepare Ni/Al-layered double hydroxides Journal of Alloys and Compounds. ,vol. 473, pp. 458- 461 ,(2009) , 10.1016/J.JALLCOM.2008.06.001
Alexis Bienvenu Béléké, Minoru Mizuhata, Electrochemical properties of nickel–aluminum layered double hydroxide/carbon composite fabricated by liquid phase deposition Journal of Power Sources. ,vol. 195, pp. 7669- 7676 ,(2010) , 10.1016/J.JPOWSOUR.2010.05.068
A. Battezzati, G. Fiorillo, A. Spadafranca, S. Bertoli, G. Testolin, Measurement of salicylic acid in human serum using stable isotope dilution and gas chromatography-mass spectrometry. Analytical Biochemistry. ,vol. 354, pp. 274- 278 ,(2006) , 10.1016/J.AB.2006.05.009
Ji Liang, Yun Zhao, Qingze Jiao, Chunhua Li, Catalytic synthesis of carbon nanostructures using layered double hydroxides as catalyst precursors Carbon. ,vol. 45, pp. 2159- 2163 ,(2007) , 10.1016/J.CARBON.2007.06.071
KunWei Li, Nobuhiro Kumada, Yoshinori Yonesaki, Takahiro Takei, Nobukazu Kinomura, Hao Wang, Chao Wang, The pH effects on the formation of Ni/Al nitrate form layered double hydroxides (LDHs) by chemical precipitation and hydrothermal method Materials Chemistry and Physics. ,vol. 121, pp. 223- 229 ,(2010) , 10.1016/J.MATCHEMPHYS.2010.01.026
S Ortega Algar, N Ramos Martos, A Molina Dı́az, Fast and single solid phase fluorescence spectroscopic batch procedure for (acetyl) salicylic acid determination in drug formulations Journal of Pharmaceutical and Biomedical Analysis. ,vol. 31, pp. 439- 446 ,(2003) , 10.1016/S0731-7085(02)00719-7