Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent “half-helicates”

作者: Christophe Lincheneau , Carole Destribats , Dawn E. Barry , Jonathan A. Kitchen , Robert D. Peacock

DOI: 10.1039/C1DT11225B

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摘要: The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) Eu(III) in CH3CN give rise to formation of lanthanide luminescent ‘half-helicates’ 1 : 3 (Ln:ligand) stoichiometry; which was observed by monitoring changes ground excited state properties ligands, time-resolved Eu-centred CPL emission.

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