Hydrolysis of Polylactic Acid (PLA) and Polycaprolactone (PCL) in Aqueous Acetonitrile Solutions: Autocatalysis

作者: Georgette L. Siparsky , Kent J. Voorhees , Fudu Miao

DOI: 10.1023/A:1022826528673

关键词:

摘要: … Polylactic acid (PLA) is being developed as a commodity plastic for disposable packaging … but quickly hydrolyze when they enter the waste stream. An understanding of the hydrolysis …

参考文章(12)
Saul Patai, The chemistry of carboxylic acids and esters UMI Books on Demand. ,(1969)
Fred W. Billmeyer, Textbook of polymer science ,(1971)
X. D. Feng (S. T. Voong), C. X. Song, W. Y. Chen, Synthesis and evaluation of biodegradable block copolymers of ɛ-caprolactone and DL-lactide Journal of Polymer Science: Polymer Letters Edition. ,vol. 21, pp. 593- 600 ,(1983) , 10.1002/POL.1983.130210802
Manoj L. Maniar, Devendra S. Kalonia, Anthony P. Simonelli, Determination of Specific Rate Constants of Specific Oligomers during Polyester Hydrolysis Journal of Pharmaceutical Sciences. ,vol. 80, pp. 778- 782 ,(1991) , 10.1002/JPS.2600800815
Yoshiharu DOI, Biodegradable Plastics and Polymers Journal of Pesticide Science. ,vol. 19, ,(1994) , 10.1584/JPESTICS.19.S11
Michel Therin, Pascal Christel, Suming Li, Henri Garreau, Michel Vert, In vivo degradation of massive poly(α-hydroxy acids): Validation of In vitro findings Biomaterials. ,vol. 13, pp. 594- 600 ,(1992) , 10.1016/0142-9612(92)90027-L
Eric A. Schmitt, D. R. Flanagan, Robert J. Linhardt, Importance of distinct water environments in the hydrolysis of poly(DL-lactide-co-glycolide) Macromolecules. ,vol. 27, pp. 743- 748 ,(1994) , 10.1021/MA00081A019
Richard A. Kenley, Maryann Ott Lee, T. Randolph Mahoney, Lynda M. Sanders, Poly(lactide-co-glycolide) decomposition kinetics in vivo and in vitro Macromolecules. ,vol. 20, pp. 2398- 2403 ,(1987) , 10.1021/MA00176A012
A. Ballara, J. Verdu, Physical aspects of the hydrolysis of polyethylene terephthalate Polymer Degradation and Stability. ,vol. 26, pp. 361- 374 ,(1989) , 10.1016/0141-3910(89)90114-6