On the intercalation of CO molecules in ultra-high vacuum conditions underneath graphene epitaxially grown on metal substrates

作者: Antonio Politano , Gennaro Chiarello

DOI: 10.1016/J.CARBON.2013.06.013

关键词:

摘要: Abstract We have studied the interaction of CO with epitaxial graphene on Pt(1 1 1) and Ru(0 0 0 1) by means high-resolution electron energy loss spectroscopy measurements. Our experiments unambiguously demonstrate that in ultra-high vacuum conditions does not intercalate underneath monolayer supported Ru(0 0 0 1). For submonolayer coverages Pt(1 1 1), adsorption occurs only Pt on-top sites while bridge sites, usually populated clean surface, are inhibited. Instead, we find is rather reactive toward water molecules.

参考文章(81)
Yu. S. Dedkov, A. M. Shikin, V. K. Adamchuk, S. L. Molodtsov, C. Laubschat, A. Bauer, G. Kaindl, Intercalation of copper underneath a monolayer of graphite on Ni(111) Physical Review B. ,vol. 64, pp. 035405- ,(2001) , 10.1103/PHYSREVB.64.035405
Antonio Politano, Gennaro Chiarello, Vibrational Investigation of Catalyst Surfaces: Change of the Adsorption Site of CO Molecules upon Coadsorption Journal of Physical Chemistry C. ,vol. 115, pp. 13541- 13553 ,(2011) , 10.1021/JP202212A
A. G. Marinopoulos, Lucia Reining, Angel Rubio, Valerio Olevano, Ab initiostudy of the optical absorption and wave-vector-dependent dielectric response of graphite Physical Review B. ,vol. 69, pp. 245419- ,(2004) , 10.1103/PHYSREVB.69.245419
G. Benedek, G. Onida, Bulk and surface dynamics of graphite with the bond charge model Physical Review B. ,vol. 47, pp. 16471- 16476 ,(1993) , 10.1103/PHYSREVB.47.16471
F.P. Netzer, J.A.D. Matthew, Adsorbate induced electron losses of CO on Pt Surface Science. ,vol. 81, pp. L651- L654 ,(1979) , 10.1016/0039-6028(79)90129-8
T. Aizawa, R. Souda, S. Otani, Y. Ishizawa, C. Oshima, Bond softening in monolayer graphite formed on transition-metal carbide surfaces Physical Review B. ,vol. 42, pp. 11469- 11478 ,(1990) , 10.1103/PHYSREVB.42.11469
Shanshan Chen, Lola Brown, Mark Levendorf, Weiwei Cai, Sang-Yong Ju, Jonathan Edgeworth, Xuesong Li, Carl W. Magnuson, Aruna Velamakanni, Richard D. Piner, Junyong Kang, Jiwoong Park, Rodney S. Ruoff, Oxidation resistance of graphene-coated Cu and Cu/Ni alloy ACS Nano. ,vol. 5, pp. 1321- 1327 ,(2011) , 10.1021/NN103028D