Carbon atoms trapped in cages: Metal carbide clusterfullerenes

作者: Peng Jin , Chengchun Tang , Zhongfang Chen

DOI: 10.1016/J.CCR.2013.10.020

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摘要: Abstract Metal carbide clusterfullerenes (MCCFs), which trap two carbon atoms together with metal atom(s) inside the fullerene cage, are a novel branch of endohedral metallofullerenes (EMFs). This review presents an exhaustive survey recent research progress in MCCFs. After detailed enumeration structural establishments representative MCCFs, their structures, intriguing cluster–cage interplays, fascinating properties, and potential applications highlighted. Moreover, variety new MCCF members suggested for future identification.

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