Facile preparation and dual catalytic activity of copper(I)-metallosalen coordination polymers
作者： Yun-Long Hou , Sheng-Xia Li , Raymond Wai-Yin Sun , Xin-Yuan Liu , Seik Weng Ng
DOI: 10.1039/C5DT00741K
关键词:
摘要: Three copper(I)–metallosalen coordination polymers (CPs), {[NiII(SalImCy)]2(CuICN)9}n (1), {[CuII(SalImCy)]2(CuICN)9}n (2) and {[NiII(SalImCy)](CuII)2·DMF}n (3) were prepared by direct combination of NiII/CuII(salen) motifs with [CuICN]n chains Cu2I2 clusters via the metalloligand strategy. The mixed-valence mixed-metal CPs could effectively catalyze both oxidation aromatic alcohols to ketones aldehydes under mild conditions photocatalytic degradation organic dye methylene blue (MB). This work demonstrates effective integration transition metal catalytic units photoactive copper(I) species in a single solid polymer meet demand for materials dual properties.
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