Design and synthesis of coordination polymers with chelated units and their application in nanomaterials science

摘要: The advances and problems associated with the preparation, properties structure of coordination polymers chelated units are presented assessed. metalloligand strategy, columnar-layered as well approaches based on supramolecular building blocks layers in design considered. conventional (solvent evaporation, diffusion, hydro(solvo)thermal, ionothermal, microfluidic, surfactant-thermal, situ spacer methods synthesis supercritical CO2) alternative (microwave-assisted, electrochemical, mechanochemical, sonochemical methods) routes described. Special attention is paid to post-synthetic preparation including modification, deprotection, exchange. thermal transformations polymers, resulting formation nanocomposite materials, bibliography includes papers published within last five years.