Preparation of dimethyltetramethoxydisilane from the disilane fraction

作者: Hamao Watanabe , Mitsunobu Kobayashi , Yuko Koike , Shigeru Nagashima , Hideyuki Matsumoto

DOI: 10.1016/S0022-328X(00)90121-9

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摘要: Abstract Reaction of sym-dimethyltetrachlorodisilane, obtained by chlorination with hydrogen chloride the higher-boiling residue produced in Direct Synthesis methylchlorosilanes, methyl orthoformate or methanol/methyl gave rise to sym-dimethyltetramethoxydisilane.

参考文章(9)
William H. Atwell, Donald R. Weyenberg, Silylene chemistry. I. The thermolysis of methoxypolysilanes Journal of the American Chemical Society. ,vol. 90, pp. 3438- 3443 ,(1968) , 10.1021/JA01015A028
E. Hengge, N. Holtschmidt, Darstellung und Eigenschaften von Methyl-methoxydisilanen Monatshefte Fur Chemie. ,vol. 99, pp. 340- 346 ,(1968) , 10.1007/BF00908939
Michael E. Childs, William P. Weber, A convenient synthesis of 1,2-dimethyltetramethoxydisilane Journal of Organometallic Chemistry. ,vol. 86, pp. 169- 173 ,(1975) , 10.1016/S0022-328X(00)89608-4
Dennis R. Rayner, Don M. Von Schriltz, J. Day, Donald J. Cram, Stereospecific interconversions of optically active sulfoxides, sulfilimines, and sulfoximines Journal of the American Chemical Society. ,vol. 90, pp. 2721- 2723 ,(1968) , 10.1021/JA01012A063
William H. Atwell, Donald R. Weyenberg, Thermolysis of methoxy-substituted polysilanes☆ Journal of Organometallic Chemistry. ,vol. 5, pp. 594- 597 ,(1966) , 10.1016/S0022-328X(00)85171-2
D. R. Weyenberg, W. H. Atwell, DIVALENT SILICON INTERMEDIATES IN THE PYROLYSIS OF ALKOXYPOLYSILANES Pure and Applied Chemistry. ,vol. 19, pp. 343- 352 ,(1969) , 10.1351/PAC196919030343
MAKOTO. KUMADA, MASAAKI. YAMAGUCHI, YOSHIHIRO. YAMAMOTO, JUN-ICHI. NAKAJIMA, KYO. SHIINA, Synthesis of Some Methyldisilanes Containing Functional Groups Journal of Organic Chemistry. ,vol. 21, pp. 1264- 1268 ,(1956) , 10.1021/JO01117A013
John W. Ryan, Redistribution and Reduction Reactions of Alkoxysilanes Journal of the American Chemical Society. ,vol. 84, pp. 4730- 4734 ,(1962) , 10.1021/JA00883A024