Graphene and cobalt phosphide nanowire composite as an anode material for high performance lithium-ion batteries

作者: Jun Yang , Yu Zhang , Chencheng Sun , Hongzheng Liu , Laiquan Li

DOI: 10.1007/S12274-015-0941-5

关键词:

摘要: The synthesis of a composite cobalt phosphide nanowires and reduced graphene oxide (denoted CoP/RGO) via facile hydrothermal method combined with subsequent annealing step is reported. resulting presents large specific surface area enhanced conductivity, which can effectively facilitate charge transport accommodates variations in volume during the lithiation/de-lithiation processes. As result, CoP/RGO nanocomposite manifests high reversible capacity 960 mA·h·g–1 over 200 cycles at current density 0.2 A·g–1 (297 10,000 20 A·g–1) excellent rate capability (424 10 A·g–1).

参考文章(48)
Juan F. Callejas, Joshua M. McEnaney, Carlos G. Read, J. Chance Crompton, Adam J. Biacchi, Eric J. Popczun, Thomas R. Gordon, Nathan S. Lewis, Raymond E. Schaak, Electrocatalytic and photocatalytic hydrogen production from acidic and neutral-pH aqueous solutions using iron phosphide nanoparticles. ACS Nano. ,vol. 8, pp. 11101- 11107 ,(2014) , 10.1021/NN5048553
Zongshuang Zhang, Jun Yang, Yanna Nuli, Baofeng Wang, Jinqiang Xu, CoPx synthesis and lithiation by ball-milling for anode materials of lithium ion cells Solid State Ionics. ,vol. 176, pp. 693- 697 ,(2005) , 10.1016/J.SSI.2004.10.017
Ran Liu, Jonathon Duay, Sang Bok Lee, Heterogeneous nanostructured electrode materials for electrochemical energy storage Chemical Communications. ,vol. 47, pp. 1384- 1404 ,(2011) , 10.1039/C0CC03158E
Wei Luo, Xianluo Hu, Yongming Sun, Yunhui Huang, Electrospun porous ZnCo2O4 nanotubes as a high-performance anode material for lithium-ion batteries Journal of Materials Chemistry. ,vol. 22, pp. 8916- 8921 ,(2012) , 10.1039/C2JM00094F
Xiaosi Zhou, Li-Jun Wan, Yu-Guo Guo, Binding SnO2 nanocrystals in nitrogen-doped graphene sheets as anode materials for lithium-ion batteries Advanced Materials. ,vol. 25, pp. 2152- 2157 ,(2013) , 10.1002/ADMA.201300071
Yuzhan Li, Zhen Zhou, X.P. Gao, Jie Yan, A novel sol–gel method to synthesize nanocrystalline LiVPO4F and its electrochemical Li intercalation performances Journal of Power Sources. ,vol. 160, pp. 633- 637 ,(2006) , 10.1016/J.JPOWSOUR.2006.01.067
Yan Yao, Matthew T. McDowell, Ill Ryu, Hui Wu, Nian Liu, Liangbing Hu, William D. Nix, Yi Cui, Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life Nano Letters. ,vol. 11, pp. 2949- 2954 ,(2011) , 10.1021/NL201470J
Sheng Han, Dongqing Wu, Shuang Li, Fan Zhang, Xinliang Feng, Graphene: A Two‐Dimensional Platform for Lithium Storage Small. ,vol. 9, pp. 1173- 1187 ,(2013) , 10.1002/SMLL.201203155
Changzhou Yuan, Hao Bin Wu, Yi Xie, Xiong Wen David Lou, Mixed Transition‐Metal Oxides: Design, Synthesis, and Energy‐Related Applications Angewandte Chemie. ,vol. 53, pp. 1488- 1504 ,(2014) , 10.1002/ANIE.201303971
Dae-Soo Yang, Dhrubajyoti Bhattacharjya, Shaukatali Inamdar, Jinsol Park, Jong-Sung Yu, Phosphorus-doped ordered mesoporous carbons with different lengths as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline media. Journal of the American Chemical Society. ,vol. 134, pp. 16127- 16130 ,(2012) , 10.1021/JA306376S