Chemical vapour deposition of titanium diboride on metallic substrates

作者: H VANDERVALK , J GRONDEL

DOI: 10.1016/0167-2738(85)90030-X

关键词:

摘要: Abstract Coating films of TiB 2 on iron, nickel, alumina, and fused silica substrates are obtained by hydrogen reduction TiCl 4 , BBr 3 in the temperature range between 700 900°C. Deposited films, treated substrate surfaces characterized X-ray diffraction, flourescence, optical microscopy, scanning electron microprobe analysis. The iron nickel suffer from etching boronising. Etching boronising controled composition reactant gas mixture, temperature, pressure reactor.

参考文章(11)
H.O. Pierson, A.W. Mullendore, The chemical vapor deposition of TiB2 from diborane Thin Solid Films. ,vol. 72, pp. 511- 516 ,(1980) , 10.1016/0040-6090(80)90540-4
T.M. Besmann, K.E. Spear, Morphology of chemical vapor deposited titanium diboride Journal of Crystal Growth. ,vol. 31, pp. 60- 65 ,(1975) , 10.1016/0022-0248(75)90111-6
H.O. Pierson, E. Randich, Titanium diboride coatings and their interaction with the substrates Thin Solid Films. ,vol. 54, pp. 119- 128 ,(1978) , 10.1016/0040-6090(78)90282-1
P. Peshev, T. Niemyski, Péparation de diborure de titane cristallin au moyen d'une réaction en phase gazeuse☆ Journal of The Less Common Metals. ,vol. 10, pp. 133- 145 ,(1966) , 10.1016/0022-5088(66)90123-8
H.O. Pierson, E. Randich, D.M. Mattox, The chemical vapor deposition of TiB2 on graphite Journal of The Less Common Metals. ,vol. 67, pp. 381- 388 ,(1979) , 10.1016/0022-5088(79)90016-X
H.O. Pierson, A.W. Mullendore, Thick boride coatings by chemical vapor deposition Thin Solid Films. ,vol. 95, pp. 99- 104 ,(1982) , 10.1016/0040-6090(82)90229-2
Aaron J. Becker, John H. Blanks, TiB2-coated cathodes for aluminum smelting cells Thin Solid Films. ,vol. 119, pp. 241- 246 ,(1984) , 10.1016/0040-6090(84)90009-9
Takehiko Takahashi, Hideo Kamiya, Chemical vapor deposition of titanium diboride Journal of Crystal Growth. ,vol. 26, pp. 203- 209 ,(1974) , 10.1016/0022-0248(74)90247-4
Theodore M. Besmann, Karl E. Spear, Analysis of the Chemical Vapor Deposition of Titanium Diboride I . Equilibrium Thermodynamic Analysis Journal of The Electrochemical Society. ,vol. 124, pp. 786- 790 ,(1977) , 10.1149/1.2133407