Some applications of the bond valence model to transition metal chalcogenides

作者: H. Boller

DOI: 10.1016/J.JALLCOM.2008.09.170

关键词:

摘要: Abstract The analysis of interatomic distances in complex transition metal chalcogenides type Am[TnSp] (A, alkali or alkaline earth metal; T, mainly Fe, Cu) can furnish interesting information on the oxidation state and also sulfur. charge distribution anions be estimated. Structural problems accommodation cations framework structures leading to disorder detected.

参考文章(13)
Herbert Boller, Herbert Blaha, Zur Kenntnis des Natriumthioferrates(III) Monatshefte Fur Chemie. ,vol. 114, pp. 145- 154 ,(1983) , 10.1007/BF00798319
M. Reissner, W. Steiner, H. Boller, 57Fe Mössbauer studies on BaFe2X3 compounds with X = S, Se Springer, Dordrecht. pp. 197- 200 ,(2002) , 10.1007/978-94-010-0281-3_49
G. Amthauer, K. Bente, Mixed-valent Iron in Synthetic Rasvumite, KFe2S3 Naturwissenschaften. ,vol. 70, pp. 146- 147 ,(1983) , 10.1007/BF00401605
J.T. Lemley, J.M. Jenks, J.T. Hoggins, Z. Eliezer, H. Steinfink, Ba15Fe7S25 and Ba3FeS5: Crystal structures, Mössbauer, magnetic, and electrical behavior Journal of Solid State Chemistry. ,vol. 16, pp. 117- 128 ,(1976) , 10.1016/0022-4596(76)90013-X
Herbert Boller, K.O. Klepp, G. Guttenbrunner, C. Spindler, Polymorphism and Disorder in Pseudo-One-Dimensional Compounds AMTS4 (A...NH4, K; M…Cu, Ag; T…Mo, W). Solid State Phenomena. pp. 285- 290 ,(2003) , 10.4028/WWW.SCIENTIFIC.NET/SSP.90-91.285
M. O'Keeffe, N. E. Brese, Bond-valence parameters for anion-anion bonds in solids Acta Crystallographica Section B-structural Science. ,vol. 48, pp. 152- 154 ,(1992) , 10.1107/S0108768191013083
M. Reissner, W. Steiner, J. Wernisch, H. Boller, Debye temperature and magnetic ordering in KxBa1−xFe2S3 Hyperfine Interactions. ,vol. 169, pp. 1301- 1304 ,(2007) , 10.1007/978-3-540-49853-7_99
I. D. Brown, D. Altermatt, Bond‐valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database Acta Crystallographica Section B-structural Science. ,vol. 41, pp. 244- 247 ,(1985) , 10.1107/S0108768185002063
N. E. Brese, M. O'Keeffe, Bond-valence parameters for solids Acta Crystallographica Section B-structural Science. ,vol. 47, pp. 192- 197 ,(1991) , 10.1107/S0108768190011041
M. O'Keeffe, A method calculating bond valences in crystals Acta Crystallographica Section A Foundations of Crystallography. ,vol. 46, pp. 138- 142 ,(1990) , 10.1107/S0108767389011104