A facile method for the preparation of novel fire-retardant layered double hydroxide and its application as nanofiller in UP
作者： Jing Cai , Hui-Min Heng , Xiao-Ping Hu , Qi-Kui Xu , Fei Miao
DOI: 10.1016/J.POLYMDEGRADSTAB.2016.01.013
关键词:
摘要: Abstract A novel functionalized layered double hydroxide (SPDP-LDH) has been prepared through hydrothermal method by co-precipitation based on spirocyclic pentaerythritol bisphosphorate disphosphoryl chlorine and Mg–Al-LDH (N-LDH). LDHs were homogenously mixed with unsaturated polyester resin (UP) to manufacture the final nanocomposites (LDH/UP). Various measurement methods have employed characterize structure, morphology, thermal stability combustible properties of intercalated LDH its hybrid composites. These data revealed that majority N-LDH was SPDP, nano-sized particles SPDP-LDH achieved. had a better dispersion in UP compared N-LDH. The TG showed initial decomposition temperatures delayed about 40 °C 50 °C for 5wt % 10wt %SPDP-LDH/UP respectively. CC presented higher fire retardancy can also be obtained SPDP-LDH/UP system decreasing value HRR THR. Compared N-LDH/UP system, an improvement mechanical properties. In particular, progressive increase 23.51% flexural strength observed at 5 wt% loading SPDP-LDH.
sci-hub.se 参考文章(54)
Raphaël Ménard, Claire Negrell, Laurent Ferry, Rodolphe Sonnier, Ghislain David, Synthesis of biobased phosphorus-containing flame retardants for epoxy thermosets comparison of additive and reactive approaches Polymer Degradation and Stability. ,vol. 120, pp. 300- 312 ,(2015) , 10.1016/J.POLYMDEGRADSTAB.2015.07.015
Tingting Cao, Li Yuan, Aijuan Gu, Guozheng Liang, Fabrication and origin of new flame retarding bismaleimide resin system with low dielectric constant and loss based on microencapsulated hexaphenoxycyclotriphosphazene in low phosphorus content Polymer Degradation and Stability. ,vol. 121, pp. 157- 170 ,(2015) , 10.1016/J.POLYMDEGRADSTAB.2015.09.004
Jing Zhan, Lei Song, Shibin Nie, Yuan Hu, Combustion properties and thermal degradation behavior of polylactide with an effective intumescent flame retardant Polymer Degradation and Stability. ,vol. 94, pp. 291- 296 ,(2009) , 10.1016/J.POLYMDEGRADSTAB.2008.12.015
Zvonimir Matusinovic, Jianxiang Feng, Charles A. Wilkie, The role of dispersion of LDH in fire retardancy: The effect of different divalent metals in benzoic acid modified LDH on dispersion and fire retardant properties of polystyrene– and poly(methyl-methacrylate)–LDH–B nanocomposites Polymer Degradation and Stability. ,vol. 98, pp. 1515- 1525 ,(2013) , 10.1016/J.POLYMDEGRADSTAB.2013.04.007
Sheng Zhang, Xishan Liu, Xiaoyu Gu, Peng Jiang, Jun Sun, Flammability and thermal behavior of polypropylene composites containing dihydrogen phosphate anion‐intercalated layered double hydroxides Polymer Composites. ,vol. 36, pp. 2230- 2237 ,(2015) , 10.1002/PC.23135
Calistor Nyambo, Dan Chen, Shengpei Su, Charles A. Wilkie, Does organic modification of layered double hydroxides improve the fire performance of PMMA Polymer Degradation and Stability. ,vol. 94, pp. 1298- 1306 ,(2009) , 10.1016/J.POLYMDEGRADSTAB.2009.03.023
Fang Song, Xile Hu, Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis Nature Communications. ,vol. 5, pp. 4477- ,(2014) , 10.1038/NCOMMS5477
Ehsan Naderi Kalali, Sergio De Juan, Xin Wang, Shibin Nie, Rui Wang, De-Yi Wang, Comparative study on synergistic effect of LDH and zirconium phosphate with aluminum trihydroxide on flame retardancy of EVA composites Journal of Thermal Analysis and Calorimetry. ,vol. 121, pp. 619- 626 ,(2015) , 10.1007/S10973-015-4598-9
De-Yi Wang, Amit Das, Francis Reny Costa, Andreas Leuteritz, Yu-Zhong Wang, Udo Wagenknecht, Gert Heinrich, Synthesis of organo cobalt-aluminum layered double hydroxide via a novel single-step self-assembling method and its use as flame retardant nanofiller in PP. Langmuir. ,vol. 26, pp. 14162- 14169 ,(2010) , 10.1021/LA102449M
Weiling Sun, Qinglin He, Yong Luo, Synthesis and properties of cinnamic acid series organic UV ray absorbents–interleaved layered double hydroxides Materials Letters. ,vol. 61, pp. 1881- 1884 ,(2007) , 10.1016/J.MATLET.2006.07.148