摘要: The microemulsion model of de Gennes et al., which is a modified version the earlier Talmon and Prager, further by imposing microscopic cell‐size cutoff. Two free‐energy minima compete lead to composite surface consisting two intersecting sheets. phase arises from one sheet oil‐ water‐rich phases with it may be in equilibrium arise other. Schulman condition, according surfactant‐film pressure equals oil–water interfacial tension, found hold good approximation middle‐phase that contains comparable amounts oil water. water‐filled domains are about 75–80 A across. That such high osmotic compressibility would opalescent or turbid due fluctuations composition. shows range equilibria like seen experiment, including two‐ three‐phase equilibria, critical poin...
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S. A. Safran, L. A. Turkevich, Phase Diagrams for Microemulsions Physical Review Letters. ,vol. 50, pp. 1930- 1933 ,(1983) , 10.1103/PHYSREVLETT.50.1930
M. Dvolaitzky, M. Guyot, M. Lagües, J. P. Le Pesant, R. Ober, C. Sauterey, C. Taupin, A structural description of liquid particle dispersions: Ultracentrifugation and small angle neutron scattering studies of microemulsions Journal of Chemical Physics. ,vol. 69, pp. 3279- 3288 ,(1978) , 10.1063/1.436979
Robert B. Griffiths, Proposal for Notation at Tricritical Points Physical Review B. ,vol. 7, pp. 545- 551 ,(1973) , 10.1103/PHYSREVB.7.545
A. M. Cazabat, D. Langevin, Diffusion of interacting particles: Light scattering study of microemulsions Journal of Chemical Physics. ,vol. 74, pp. 3148- 3158 ,(1981) , 10.1063/1.441525
Eric W. Kaler, Karl E. Bennett, H. Ted Davis, L. E. Scriven, Toward understanding microemulsion microstructure: A small‐angle x‐ray scattering study The Journal of Chemical Physics. ,vol. 79, pp. 5673- 5684 ,(1983) , 10.1063/1.445688
A. Pouchelon, D. Chatenay, J. Meunier, D. Langevin, Origin of low interfacial tensions in systems involving microemulsion phases joint international conference on information sciences. ,vol. 82, pp. 418- 422 ,(1981) , 10.1016/0021-9797(81)90383-0
A.M. Cazabat, D. Langevin, J. Meunier, A. Pouchelon, Critical behavior in microemulsions Advances in Colloid and Interface Science. ,vol. 16, pp. 175- 199 ,(1982) , 10.1016/0001-8686(82)85016-1
Robert B. Griffiths, Thermodynamics Near the Two-Fluid Critical Mixing Point in He 3 - He 4 Physical Review Letters. ,vol. 24, pp. 715- 717 ,(1970) , 10.1103/PHYSREVLETT.24.715
J. Biais, M. Mercier, P. Bothorel, B. Clin, P. Lalanne, B. Lemanceau, Microemulsions and electron microscopy Journal of Microscopy. ,vol. 121, pp. 169- 178 ,(1981) , 10.1111/J.1365-2818.1981.TB01209.X
J. BIAIS, P. BOTHOREL, B. CLIN, P. LALANNE, THEORETICAL BEHAVIOUR OF MICROEMULSIONS GEOMETRICAL ASPECTS, DILUTION PROPERTIES AND ROLE OF ALCOHOL.COMPARISON WITH EXPERIMENTAL RESULTS. Journal of Dispersion Science and Technology. ,vol. 2, pp. 67- 95 ,(1981) , 10.1080/01932698108943900