Melting kinetics in polymers
作者： D. R. Lippits , S. Rastogi , G. W. H. Höhne
DOI: 10.1103/PHYSREVLETT.96.218303
关键词:
摘要: In polymers, it is possible to obtain single chain forming crystals. It feasible melt these crystals by simple consecutive detachment of segments from the crystalline substrate and its diffusion into melt. However, complication in melting process occurs when surface shared between different Experimentally, a clear distinction processes observed, differences activation energies required for or having topological constraints. The free starts at temperature predicted Gibbs-Thomson equation, whereas higher time if has overcome
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