X-Ray Fluorescence Spectroscopy of Inorganic Solids. III. SiKαandKβSpectra in Binary Silicates
作者： Niro Kikuchi , Takashi Maekawa , Toshio Yokokawa
DOI: 10.1246/BCSJ.52.1260
关键词:
摘要: The Si Kα and Kβ spectra of several silicates were measured. showed negative energy shifts referred to SiO2; these are consistent with the results for binary silicate glasses. On other hand, positive absolute values about ten times as large in each compound. A linear relation was observed between shifts. 1s shift orthosilicate estimated from spectral splitting Na2Si2O5. stability silicon–oxygen bond discussed aid 1s. above suggests that strength is lowered (the increased) decreasing Goulombic interaction (lowering energy) silicon oxygen silicates.
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