High reusability and durability of carbon-doped TiO 2 /carbon nanofibrous film as visible-light-driven photocatalyst
作者： Lixin Song , Wanru Jing , Jingjing Chen , Shouren Zhang , Yuqing Zhu
DOI: 10.1007/S10853-018-3105-7
关键词:
摘要: The light response range, reusability, and durability of photocatalyst are the key issues for its practical application. To address these problems, C-doped TiO2/carbon nanofibrous (CTCNF) film with incorporation TiO2 nanoparticles into carbon nanofibers was prepared by electrospinning calcination (pre-oxidation carbonization). All obtained CTCNF films exhibited a promising absorption in ultraviolet–visible region. With optimization carbonization temperature, carbonized at 800 °C (CTCNF-800) showed strongest absorption. Consequently, CTCNF-800 possessed highest photocatalytic degradation efficiency 94.2% rhodamine B. In addition, excellent flexibility deserved mechanical strength, hence, could be easily segregated from solution recycled. Satisfyingly, still exceeded 92% after using six cycles, implying that had reusability well stability. Besides, over 90% kept air without illumination 1 year, indicating outstanding durability. demonstrates tremendous potential application purification wastewater.
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Jian Tian, Yanhua Leng, Hongzhi Cui, Hong Liu, Hydrogenated TiO2 nanobelts as highly efficient photocatalytic organic dye degradation and hydrogen evolution photocatalyst Journal of Hazardous Materials. ,vol. 299, pp. 165- 173 ,(2015) , 10.1016/J.JHAZMAT.2015.06.019
Qiuying Yi, Yi Zhou, Mingyang Xing, Jinlong Zhang, Vacuum activation-induced Ti 3+ and carbon co-doped TiO 2 with enhanced solar light photo-catalytic activity Research on Chemical Intermediates. ,vol. 42, pp. 4181- 4189 ,(2016) , 10.1007/S11164-015-2268-Y
Donghua Teng, Yunhua Yu, Haiyang Liu, Xiaoping Yang, Seungkon Ryu, Yuanhua Lin, Facile fabrication of heterostructured TiO2−xNx/CNFs as an efficient visible-light responsive photocatalyst Catalysis Communications. ,vol. 10, pp. 442- 446 ,(2009) , 10.1016/J.CATCOM.2008.10.027
Soonhyun Kim, Sang Kyoo Lim, Preparation of TiO2-embedded carbon nanofibers and their photocatalytic activity in the oxidation of gaseous acetaldehyde Applied Catalysis B-environmental. ,vol. 84, pp. 16- 20 ,(2008) , 10.1016/J.APCATB.2008.02.025
Wenxi Guo, Fang Zhang, Changjian Lin, Zhong Lin Wang, Direct Growth of TiO2 Nanosheet Arrays on Carbon Fibers for Highly Efficient Photocatalytic Degradation of Methyl Orange Advanced Materials. ,vol. 24, pp. 4761- 4764 ,(2012) , 10.1002/ADMA.201201075
Juming Liu, Qiancheng Zhang, Jucai Yang, Huiyan Ma, Moses O. Tade, Shaobin Wang, Jian Liu, Facile synthesis of carbon-doped mesoporous anatase TiO2 for the enhanced visible-light driven photocatalysis Chemical Communications. ,vol. 50, pp. 13971- 13974 ,(2014) , 10.1039/C4CC05544F
Peng Zhang, Changlu Shao, Zhenyi Zhang, Mingyi Zhang, Jingbo Mu, Zengcai Guo, Yangyang Sun, Yichun Liu, Core/shell nanofibers of TiO2@carbon embedded by Ag nanoparticles with enhanced visible photocatalytic activity Journal of Materials Chemistry. ,vol. 21, pp. 17746- 17753 ,(2011) , 10.1039/C1JM12965A
Nan Wu, Yingde Wang, Yongpeng Lei, Bing Wang, Cheng Han, Flexible N–doped TiO2/C ultrafine fiber mat and its photocatalytic activity under simulated sunlight Applied Surface Science. ,vol. 319, pp. 136- 142 ,(2014) , 10.1016/J.APSUSC.2014.06.108
Zhifeng Wang, Kohji Yoshinaga, Xiu R. Bu, Ming Zhang, Low temperature fabrication & photocatalytical activity of carbon fiber-supported TiO2 with different phase compositions. Journal of Hazardous Materials. ,vol. 290, pp. 134- 141 ,(2015) , 10.1016/J.JHAZMAT.2015.01.033
Yongmei Wu, Mingyang Xing, Jinlong Zhang, Gel-hydrothermal synthesis of carbon and boron co-doped TiO2 and evaluating its photocatalytic activity Journal of Hazardous Materials. ,vol. 192, pp. 368- 373 ,(2011) , 10.1016/J.JHAZMAT.2011.05.037