Sequential extraction of mass spectra and chromatographic profiles from overlapping gas chromatography-mass spectroscopy signals.

作者: Zhichao Liu , Wensheng Cai , Xueguang Shao

DOI: 10.1016/J.CHROMA.2008.03.014

关键词:

摘要: For resolution of multicomponent overlapping GC/MS signals, a window independent component analysis (WICA) is proposed. In WICA, the information, i.e., existing interval along retention time, each obtained. Then, with data in selective (non-overlapping) window, mass spectrum first extracted by using (ICA), and ions, chromatographic profile calculated. With subtraction information from matrix, next can be this way, sequentially time. Due to usage limitation ICA analytical signals overcome. Two experimental are analyzed proposed WICA. Results show that both spectra profiles components signal accurately extracted.

参考文章(35)
Marcel Maeder, Arne Zilian, Evolving factor analysis, a new multivariate technique in chromatography Chemometrics and Intelligent Laboratory Systems. ,vol. 3, pp. 205- 213 ,(1988) , 10.1016/0169-7439(88)80051-0
Rolf Manne, Hailin Shen, Yizeng Liang, Subwindow factor analysis Chemometrics and Intelligent Laboratory Systems. ,vol. 45, pp. 171- 176 ,(1999) , 10.1016/S0169-7439(98)00101-4
Bernard. Vandeginste, Raymond. Essers, Theo. Bosman, Joost. Reijnen, Gerrit. Kateman, Three-component curve resolution in liquid chromatography with multiwavelength diode array detection Analytical Chemistry. ,vol. 57, pp. 971- 985 ,(1985) , 10.1021/AC00283A005
J.Y. Ren, C.Q. Chang, P.C.W. Fung, J.G. Shen, F.H.Y. Chan, Free radical EPR spectroscopy analysis using blind source separation. Journal of Magnetic Resonance. ,vol. 166, pp. 82- 91 ,(2004) , 10.1016/J.JMR.2003.10.015
Kathleen J. Schostack, Edmund R. Malinowski, Investigation of window factor analysis and matrix regression analysis in chromatography Chemometrics and Intelligent Laboratory Systems. ,vol. 20, pp. 173- 182 ,(1993) , 10.1016/0169-7439(93)80013-8
Christian Jutten, Jeanny Herault, Blind separation of sources, Part 1: an adaptive algorithm based on neuromimetic architecture Signal Processing. ,vol. 24, pp. 1- 10 ,(1991) , 10.1016/0165-1684(91)90079-X
Scott Makeig, Marissa Westerfield, T-P Jung, Sonia Enghoff, Jeanne Townsend, Eric Courchesne, Terrence J Sejnowski, Dynamic Brain Sources of Visual Evoked Responses Science. ,vol. 295, pp. 690- 694 ,(2002) , 10.1126/SCIENCE.1066168