On-surface generation and imaging of arynes by atomic force microscopy

作者: Niko Pavliček , Bruno Schuler , Sara Collazos , Nikolaj Moll , Dolores Pérez

DOI: 10.1038/NCHEM.2300

关键词:

摘要: Based initially on the outcome of certain reactions but later backed up by spectroscopic evidence, chemists have proposed — for more than a century existence arynes as extremely reactive intermediates in chemical transformations. Now, with help atomic force microscopy, it is finally possible to generate and directly visualize this elusive intermediate.

参考文章(50)
Adam E. Goetz, Neil K. Garg, Regioselective reactions of 3,4-pyridynes enabled by the aryne distortion model Nature Chemistry. ,vol. 5, pp. 54- 60 ,(2013) , 10.1038/NCHEM.1504
Hans Henning Wenk, Michael Winkler, Wolfram Sander, One Century of Aryne Chemistry Angewandte Chemie International Edition. ,vol. 42, pp. 502- 528 ,(2003) , 10.1002/ANIE.200390151
Reinhard W. Hoffmann, Keisuke Suzuki, A “Hot, Energized” Benzyne Angewandte Chemie. ,vol. 52, pp. 2655- 2656 ,(2013) , 10.1002/ANIE.201209041
Jinchong Xiao, Hieu M. Duong, Yi Liu, Wenxiong Shi, Li Ji, Gang Li, Shuzhou Li, Xue-Wei Liu, Jan Ma, Fred Wudl, Qichun Zhang, Synthesis and Structure Characterization of a Stable Nonatwistacene Angewandte Chemie. ,vol. 51, pp. 6094- 6098 ,(2012) , 10.1002/ANIE.201200949
Dawen Niu, Patrick H. Willoughby, Brian P. Woods, Beeraiah Baire, Thomas R. Hoye, Alkane desaturation by concerted double hydrogen atom transfer to benzyne Nature. ,vol. 501, pp. 531- 534 ,(2013) , 10.1038/NATURE12492
Aidi Zhao, Qunxiang Li, Lan Chen, Hongjun Xiang, Weihua Wang, Shuan Pan, Bing Wang, Xudong Xiao, Jinlong Yang, JG Hou, Qingshi Zhu, Controlling the Kondo effect of an adsorbed magnetic ion through its chemical bonding. Science. ,vol. 309, pp. 1542- 1544 ,(2005) , 10.1126/SCIENCE.1113449
Thomas R. Hoye, Beeraiah Baire, Dawen Niu, Patrick H. Willoughby, Brian P. Woods, The hexadehydro-Diels–Alder reaction Nature. ,vol. 490, pp. 208- 212 ,(2012) , 10.1038/NATURE11518
R. Stoermer, B. Kahlert, Ueber das 1- und 2-Brom-cumaron Berichte der deutschen chemischen Gesellschaft. ,vol. 35, pp. 1633- 1640 ,(1902) , 10.1002/CBER.19020350286
Bruno Schuler, Sara Collazos, Leo Gross, Gerhard Meyer, Dolores Pérez, Enrique Guitián, Diego Peña, From Perylene to a 22‐Ring Aromatic Hydrocarbon in One‐Pot Angewandte Chemie. ,vol. 53, pp. 9004- 9006 ,(2014) , 10.1002/ANIE.201403707