From Perylene to a 22‐Ring Aromatic Hydrocarbon in One‐Pot
作者： Bruno Schuler , Sara Collazos , Leo Gross , Gerhard Meyer , Dolores Pérez
关键词: Aryne 、 Aromatic hydrocarbon 、 Molecule 、 Perylene 、 Atomic resolution 、 Chemistry 、 Ring (chemistry) 、 Benzene 、 Photochemistry 、 Scanning probe microscopy
摘要: The successful synthesis of a threefold symmetric C78H36 molecule with 22 fused benzene rings is reported. This clover-shaped nanographene was characterized on an ultrathin insulating film atomic resolution by scanning probe microscopy.
sci-hub.se 参考文章(24)
Dolores Pérez, Diego Peña, Enrique Guitián, Aryne Cycloaddition Reactions in the Synthesis of Large Polycyclic Aromatic Compounds European Journal of Organic Chemistry. ,vol. 2013, pp. 5981- 6013 ,(2013) , 10.1002/EJOC.201300470
Jascha Repp, Gerhard Meyer, Sladjana M. Stojković, André Gourdon, Christian Joachim, Molecules on Insulating Films: Scanning-Tunneling Microscopy Imaging of Individual Molecular Orbitals Physical Review Letters. ,vol. 94, pp. 026803- 026803 ,(2005) , 10.1103/PHYSREVLETT.94.026803
L. Gross, F. Mohn, N. Moll, P. Liljeroth, G. Meyer, The Chemical Structure of a Molecule Resolved by Atomic Force Microscopy Science. ,vol. 325, pp. 1110- 1114 ,(2009) , 10.1126/SCIENCE.1176210
D. G. de Oteyza, P. Gorman, Y.-C. Chen, S. Wickenburg, A. Riss, D. J. Mowbray, G. Etkin, Z. Pedramrazi, H.-Z. Tsai, A. Rubio, M. F. Crommie, F. R. Fischer, Direct Imaging of Covalent Bond Structure in Single-Molecule Chemical Reactions Science. ,vol. 340, pp. 1434- 1437 ,(2013) , 10.1126/SCIENCE.1238187
Christopher D. Simpson, J. Diedrich Brand, Alexander J. Berresheim, Laurence Przybilla, Hans Joachim Räder, Klaus Müllen, Synthesis of a giant 222 carbon graphite sheet. Chemistry: A European Journal. ,vol. 8, pp. 1424- 1429 ,(2002) , 10.1002/1521-3765(20020315)8:6<1424::AID-CHEM1424>3.0.CO;2-Z
Katsuaki Kawasumi, Qianyan Zhang, Yasutomo Segawa, Lawrence T. Scott, Kenichiro Itami, A grossly warped nanographene and the consequences of multiple odd-membered-ring defects Nature Chemistry. ,vol. 5, pp. 739- 744 ,(2013) , 10.1038/NCHEM.1704
Xin Yan, Xiao Cui, Liang-shi Li, Synthesis of large, stable colloidal graphene quantum dots with tunable size. Journal of the American Chemical Society. ,vol. 132, pp. 5944- 5945 ,(2010) , 10.1021/JA1009376
Hieu M. Duong, Michael Bendikov, Daniel Steiger, Qichun Zhang, Gursel Sonmez, Jeffrey Yamada, Fred Wudl, Efficient Synthesis of a Novel, Twisted and Stable, Electroluminescent “Twistacene” Organic Letters. ,vol. 5, pp. 4433- 4436 ,(2003) , 10.1021/OL035751V
L. Gross, F. Mohn, N. Moll, B. Schuler, A. Criado, E. Guitian, D. Pena, A. Gourdon, G. Meyer, Bond-order discrimination by atomic force microscopy. Science. ,vol. 337, pp. 1326- 1329 ,(2012) , 10.1126/SCIENCE.1225621
Shengxiong Xiao, Seok Ju Kang, Ying Wu, Seokhoon Ahn, Jong Bok Kim, Yueh-Lin Loo, Theo Siegrist, Michael L. Steigerwald, Hexing Li, Colin Nuckolls, Supersized contorted aromatics Chemical Science. ,vol. 4, pp. 2018- 2023 ,(2013) , 10.1039/C3SC50374G