Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

作者: Amlan K. Pal , Philippe D. Ducharme , Garry S. Hanan

DOI: 10.1039/C3CC47856D

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摘要: The diastereoselective formation of a meso-dinuclear Ru(II) complex novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. design the ligand, parallel coordination vectors, induces diastereoselectivity 1 : 13 : 1 [ΛΛ : (ΛΔ or ΔΛ) : ΔΔ] for dinuclear complex.

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